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The mechanism of PuVI oxidation with ozone and other reagents in alkaline solutions

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Abstract

The analysis of reported data on the interaction of ozone with alkaline solutions of PuVI leads to the conclusion that the process of ozonation involves reactions O3 + OH– → HO -2 + O2, O3 + + HO -2 + OH– → O -3 + O -2 + H2O and O3 + O -2 → O -3 + O2. The O -3 radical ion oxidizes PuVI, the HO -2 and O -2 anions reduce PuVII and PuVI and react with O -3 . Using persulfate instead of O3 in aerated solution at 80—95 °C results in thermal decomposition of the S2O 2-8 anion into radical ions of SO -4 , oxidizing OH– to the O– ion, which in reaction with O2 forms O -3 . The oxidation of PuVI proceeds via the formation of an activated complex with O -3 . where charge transfer occurs with the simultaneous elimination of two H+ ions. A similar mechanism is operating in reactions of PuVI with BrO–, Fe(CN) 3–6 , AmVI, and AmVII. Upon the γ-radiolysis of alkaline solutions of PuVI saturated with N2O or containing S2O 2–8 , e –aq is converted into O– and then into O -3 ; F2 and XeF2 in alkaline solutions are decomposed with the formation of H2O2, which prevents producing PuVII.

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References

  1. N. N. Krot, A. D. Gel’man, Dokl. Akad. Nauk SSSR, 1967, 177, 124 [Dokl. Chem. (Engl. Transl.), 1967].

    CAS  Google Scholar 

  2. Yu. A. Komkov, N. N. Krot, A. D. Gel’man, Sov. Radiochem. (Engl. Transl.), 1968, 10, 625 [Radiokhimiya, 1968, 10, 625].

    CAS  Google Scholar 

  3. M. P. Mefod’eva, N. N. Krot, T. V. Afonas’eva, Radiokhimiya, 1977, 19, 245 [Sov. Radiochem. (Engl. Transl.), 1977, 19, No. 2].

    Google Scholar 

  4. V. P. Shilov, A. M. Fedoseev, B. G. Ershov, Radiokhimiya, 2012, 54, 297 [Sov. Radiochem. (Engl. Transl.), 2012, 54, No. 4].

    Google Scholar 

  5. I. Fabian, Pure App. Chem., 2006, 78, 1559.

    Article  CAS  Google Scholar 

  6. I. Staehelin, I. Hoigne, Environ. Sci. Technol., 1982, 16, 676.

    Article  CAS  Google Scholar 

  7. K. Sehested, I. Holcman, E. I. Hart, J. Phys. Chem., 1983, 87, 1951.

    Article  CAS  Google Scholar 

  8. V. P. Shilov, A. V. Gogolev, A. M. Fedoseev, Radiokhimiya, 2015, 57, 337–338 [Russ. Radiochem. (Engl. Transl.), 2015, 57, No. 4].

    Google Scholar 

  9. V. P. Shilov, A. V. Gogolev, A. K. Pikaev, High Energy Chem. (Engl. Transl.), 1998, 32, 354 [Khimiya vysokikh energii, 1998, 32, 395].

    CAS  Google Scholar 

  10. V. P. Shilov, N. A. Budantseva, Radiochem. (Engl. Transl.), 1998, 40, 568 [Radiokhimiya, 1998, 40, 546].

    CAS  Google Scholar 

  11. Yu. A. Komkov, N. N. Krot, Radiokhimiya, 1970, 12, 227 [Sov. Radiochem. (Engl. Transl.), 1970, 12, No. 2].

    CAS  Google Scholar 

  12. V. R. Landi, L. J. Heidt, J. Phys. Chem., 1969, 73, 2361.

    Article  CAS  Google Scholar 

  13. N. N. Krot, A. D. Gel’man, M. P. Mefod’eva, V. P. Shilov, V. F. Peretrukhin, V. I. Spitsyn, Semivalentnoe sostoyanie neptuniya, plutoniya i ameritsiya [Heptavalent State of Neptunium, Plutonium, and Americium], Nauka, Moscow, 1977, 149 pp. (in Russian).

    Google Scholar 

  14. V. P. Shilov, Russ. Radiochem. (Engl. Transl.), 1998, 40, 11–16 [Radiokhimiya, 1998, 40, 12].

    CAS  Google Scholar 

  15. V. F. Peretrukhin, K. Delegard, V. P. Shilov, XIII Intern. Workshop Fundamental Properties of Plutonium, Workshop Trans. (Sarov, September 9–13, 2013), Sarov, 2013, 284–288 [Mater. 13-go Mezhdunar. Seminara “Fundamental’nye svoistva plutoniya” (Sarov, 9–13 sentyabrya 2013), VNIIEF, Sarov, 279–283].

  16. Yu. A. Komkov, V. F. Peretrukhin, N. N. Krot, A. D. Gel’man, Sov. Radiochem. (Engl. Transl.), 1969, 11, 398–402 [Radiokhimiya, 1969, 11, 407].

    Google Scholar 

  17. V. P. Shilov, A. A. Bessonov, A. M. Fedoseev, Russ. Radiochem. (Engl. Transl.), 2009, 51, 594 [Radiokhimiya, 2009, 51, 519].

    CAS  Google Scholar 

  18. V. B. Nikolaevsky, V. P. Shilov, N. N. Krot, Radiokhimiya, 1974, 16, 122 [Sov. Radiochem. (Engl. Transl.), 1974, 16].

    Google Scholar 

  19. N. N. Krot, V. P. Shilov, V. B. Nikolaevskii, A. K. Pikaev, A. D. Gel’man, V. I. Spitsyn, Dokl. Chem. (Engl. Transl.), 1974, 217, 525 [Dokl. Akad. Nauk SSSR, 1974, 217, 589].

    Google Scholar 

  20. A. K. Pikaev, V. P. Shilov, N. N. Krot, A. D. Gel’man, V. I. Spytsin, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1969, 18, 1111 [Izv. Akad. Nauk SSSR, Ser. Khim., 1969, 1199].

    Article  Google Scholar 

  21. F. A. Zakharova, A. K. Pikaev, M. M. Orlova, A. D. Gel’man, V. I. Spitsyn, Dokl. Phys. Chem. (Engl. Transl.), 1971, 201, 996 [Dokl. Akad. Nauk SSSR, 1971, 201, 636].

    Google Scholar 

  22. A. K. Pikaev, S. A. Kabakchi, Reaktsionnaya sposobnost’ pervichnykh productov radioliza vody [Reactivity of Primary Products of Water Radiolysis], Energoizdat, Moscow, 1982, 201 pp. (in Russian).

    Google Scholar 

  23. A. K. Pikaev, V. P. Shilov, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1978, 27, 1886 [Izv. Akad. Nauk SSSR, Ser. Khim., 1978, 2136].

    Article  Google Scholar 

  24. P. K. Bhattacharyya, R. D. Saini, Radiat. Eff. Lett., 1981, 57, No. 6, 165.

    Article  CAS  Google Scholar 

  25. V. F. Peretrukhin, N. N. Krot, A. D. Gel’man, Radiokhimiya, 1972, 14, 633 [Sov. Radiochem. (Engl. Transl.), 1972, 14, No. 4].

    CAS  Google Scholar 

  26. Yu. K. Gusev, V. F. Peretrukhin, V. P. Shilov, I. S. Kirin, Radiokhimiya, 1972, 14, 888 [Sov. Radiochem. (Engl. Transl.), 1972, 14, No. 6].

    CAS  Google Scholar 

  27. V. P. Domanov, G. V. Baklanov, Yu. A. Lobanov, JINR GLNR Scientific Reports, 1997–1998, E7-2000-232, 167–168.

  28. V. P. Domanov, G. V. Baklanov, Yu. A. Lobanov, Radiokhimiya, 2002, 44, 106–112 [Russ. Radiochem. (Engl. Transl.), 2002, 44, No. 2].

    Google Scholar 

  29. S. Hübener, St. Taut, A. Vahle, G. Bernhard, Th. Fanghänel, Radiochimica Acta, 2008, 96, 781–785.

    Article  Google Scholar 

  30. M. V. Nikonov, A. V. Gogolev, I. G. Tananaev, B. F. Myasoedov, Radiokhimiya, 2004, 46, 312–314 [Russ. Radiochem. (Engl. Transl.), 2004, 46, No. 4].

    Google Scholar 

  31. I. G. Tananaev, M. V. Nikonov, B. F. Myasoedov, D. L. Clark, J. Alloys Comp., 2007, 444–445, 668–672.

    Article  Google Scholar 

  32. M. R. Antonio, C. W. Williams, J. A. Sullivan, S. Skanthacumar, Hu. Yung-Jin, L. Soderholm, Inorg. Chem., 2012, 51, 5274–5284.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Build. 4, 31 Leninsky prosp., 119071, Moscow, Russian Federation

    V. P. Shilov, A. V. Gogolev, A. M. Fedosseev & B. G. Ershov

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  1. V. P. Shilov
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  2. A. V. Gogolev
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  3. A. M. Fedosseev
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  4. B. G. Ershov
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Correspondence to A. V. Gogolev.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2351—2354, October, 2016.

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Shilov, V.P., Gogolev, A.V., Fedosseev, A.M. et al. The mechanism of PuVI oxidation with ozone and other reagents in alkaline solutions. Russ Chem Bull 65, 2351–2354 (2016). https://doi.org/10.1007/s11172-016-1587-5

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  • DOI: https://doi.org/10.1007/s11172-016-1587-5

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