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Synthesis, structure, and properties of a new bifunctional radical cation salt with ferracarborane anion: (BEDT-TTF)2[8,8´-Cl2-3,3´-Fe(1,2-C2B9H10)2]

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Abstract

A new radical cation salt of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) with iron(III) bis(1,2-dicarbollide) 8,8´-dichloro derivatives, that is (BEDT-TTF)2[8,8´-Cl2-3,3´-Fe-(1,2-C2B9H10)2], was synthesized. Its electroconducting and magnetic characteristics were studied, molecular and crystal structures were determined. The electroconductivity of crystals at room temperature was σ293 ~5 Ω–1 cm–1, which is close to the corresponding value for the salt of cobalt bis(1,2-dicarbollide) dichloro derivative and is considerably higher than the electroconductivity of a similar salt of unsubstituted iron bis(1,2-dicarbollide). The measurements of magnetic susceptibility at 2—300 K showed that this salt is paramagnetic.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    O. N. Kazheva, L. I. Buravov & O. A. Dyachenko

  2. V. N. Karazin Kharkov National University, 4 pl. Svobody, 61022, Kharkov, Ukraine

    A. V. Kravchenko & D. M. Chudak

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    G. G. Aleksandrov

  4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. D. Kosenko, I. A. Lobanova & V. I. Bregadze

  5. Institute of Solid State Physics, Russian Academy of Sciences, 2 ul. Akad. Osip´yana, 142432, Chernogolovka, Moscow Region, Russian Federation

    S. G. Protasova

  6. Institute of Chemistry, Jan Kochanowski University in Kielce, 5 ul. Zeromskiego, 25-369, Kielce, Poland

    V. A. Starodub

Authors
  1. O. N. Kazheva
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  2. A. V. Kravchenko
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  3. G. G. Aleksandrov
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  4. I. D. Kosenko
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  5. I. A. Lobanova
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  6. V. I. Bregadze
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  7. D. M. Chudak
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  8. L. I. Buravov
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  9. S. G. Protasova
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  10. V. A. Starodub
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  11. O. A. Dyachenko
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Corresponding author

Correspondence to I. D. Kosenko.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2195—2201, September, 2016.

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Kazheva, O.N., Kravchenko, A.V., Aleksandrov, G.G. et al. Synthesis, structure, and properties of a new bifunctional radical cation salt with ferracarborane anion: (BEDT-TTF)2[8,8´-Cl2-3,3´-Fe(1,2-C2B9H10)2]. Russ Chem Bull 65, 2195–2201 (2016). https://doi.org/10.1007/s11172-016-1567-9

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  • DOI: https://doi.org/10.1007/s11172-016-1567-9

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