Skip to main content
SpringerLink
Log in

[2+2] Cycloaddition of the Schrock titanium silylidene and acetylene

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

[2+2] Cycloadduct of the titanium silylidene Cp2Ti(thf)=Si[Si3(SiMeBut 2)4] and acetylene was readily prepared, isolated, and characterized by NMR spectroscopy and computational studies of the Me3Si-substituted model. Geometric features of the model, based on its optimized geometry, suggest that the best structural description for such [2+2] cycloadduct is a metallacycle rather than a π complex.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Handbook of Metathesis, Ed. R. H. Grubbs, Wiley, Weinheim, 2003, Vols 1–3

  2. J.-L. Hérisson, Y. Chauvin, Makromol. Chem., 1971, 141, 161.

    Article  Google Scholar 

  3. E. L. Dias, S. T. Nguyen, R. H. Grubbs, J. Am. Chem. Soc., 1997, 119, 3887

    Article  CAS  Google Scholar 

  4. R. R. Schrock, Tetrahedron, 1999, 55, 8141.

    Article  CAS  Google Scholar 

  5. V. Ya. Lee, S. Aoki, T. Yokoyama, S. Horiguchi, A. Sekiguchi, H. Gornitzka, J.-D. Guo, S. Nagase, J. Am. Chem. Soc., 2013, 135, 2987.

    Article  CAS  Google Scholar 

  6. N. A. Petasis, D.-K. Fu, Organometallics, 1993, 12, 3776

    Article  CAS  Google Scholar 

  7. K. M. Doxsee, J. J. J. Juliette, J. K. M. Mouser, K. Zientara, Organometallics, 1993, 12, 4742.

    Article  CAS  Google Scholar 

  8. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, O. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski, D. J. Fox, Gaussian 09, Revision D. 01, Gaussian, Inc., Wallingford (CT), 2013.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Graduate School of Pure and Applied Sciences, Department of Chemistry, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, 305–8571, Ibaraki, Japan

    V. Ya. Lee, S. Horiguchi & A. Sekiguchi

  2. Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    O. A. Gapurenko & V. I. Minkin

Authors
  1. V. Ya. Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. A. Gapurenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Minkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. Horiguchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Sekiguchi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. Ya. Lee.

Additional information

Based on the Materials of the XIII Andrianov Conference "Organosilicon Compounds: Synthesis, Properties, and Application" (June 28—July 1, 2015, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1139—1141, April, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lee, V.Y., Gapurenko, O.A., Minkin, V.I. et al. [2+2] Cycloaddition of the Schrock titanium silylidene and acetylene. Russ Chem Bull 65, 1139–1141 (2016). https://doi.org/10.1007/s11172-016-1425-9

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-016-1425-9

Keywords

Search

Navigation