Skip to main content
SpringerLink
Log in

Hybrid azobenzene-doped nanoporous polymers derived from cubic octavinylsilsesquioxane

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A series of novel hybrid porous polymers (HPPs) with high specific surface areas were first prepared by one-step ternary cross-linking copolymerization of octavinylsilsesquioxane (OVS), 1,3,5-tribromobenzene, and 4,4´-dibromoazobenzene via the Heck reaction. The porosities and the CO2 uptake capacities of resulting azobenzene-doped porous polymers could be tuned by modulating the molar percentage of the azo units. At 273 K and 101 kPa, the sample with the specific surface area of ~700 m2 g–1 (data of Brunauer—Emmett—Teller (BET) surface area analysis) showed the highest CO2 uptake of 5.45 wt.% (1.20 mmol g–1) among the fabricated HPPs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Germain, J. M. Fréchet, F. Svec, Small, 2009, 5, 1098.

    Article  CAS  Google Scholar 

  2. R. Dawson, A. I. Cooper, D. J. Adams, Prog. Polym. Sci., 2012, 37, 530.

    Article  CAS  Google Scholar 

  3. N. Du, H. B. Park, G. P. Robertson, M. M. Dal-Cin, T. Visser, L. Scoles, M. D. Guiver, Nat. Mater., 2011, 10, 372.

    Article  CAS  Google Scholar 

  4. C. G. Bezzu, M. Carta, A. Tonkins, J. C. Jansen, P. Bernardo, F. Bazzarelli, N. B. McKeown, Adv. Mater., 2012, 24, 5930.

    Article  CAS  Google Scholar 

  5. J. Schmidt, J. Weber, J. D. Epping, M. Antonietti, A. Thomas, Adv. Mater., 2009, 21, 702.

    Article  CAS  Google Scholar 

  6. G. J. D. A. Soler-Illia, C. Sanchez, B. Lebeau, J. Patarin, Chem. Rev., 2002, 102, 4093.

    Article  Google Scholar 

  7. N. B. McKeown, P. M. Budd, Chem. Soc. Rev., 2006, 35, 675.

    Article  CAS  Google Scholar 

  8. D. Wu, F. Xu, B. Sun, R. Fu, H. He, K. Matyjaszewski, Chem. Rev., 2012, 112, 3959.

    Article  CAS  Google Scholar 

  9. L. Sun, Z. Liang, J. Yu, Polym. Chem., 2015, 6, 917.

    Article  CAS  Google Scholar 

  10. W. Yang, X. Jiang, H. Liu, RSC Adv., 2015, 5, 12800.

    Article  CAS  Google Scholar 

  11. S. Wan, J. Guo, J. Kim, H. Ihee, D. Jiang, Angew. Chem., 2008, 120, 8958.

    Article  Google Scholar 

  12. R. Dawson, D. J. Adams, A. I. Cooper, Chem. Sci., 2011, 2, 1173.

    Article  CAS  Google Scholar 

  13. U. H. Bunz, K. Seehafer, F. L. Geyer, M. Bender, I. Braun, E. Smarsly, J. Freudenberg, Macromol. Rapid Commun., 2014, 35, 1466.

    Article  CAS  Google Scholar 

  14. Y. Wu, D. Wang, L. Li, W. Yang, S. Feng, H. Liu, J. Mater. Chem. A, 2014, 2, 2160.

    Article  CAS  Google Scholar 

  15. H. Urakami, K. Zhang, F. Vilela, Chem. Commun., 2013, 49, 2353.

    Article  CAS  Google Scholar 

  16. B. Kiskan, J. Weber, ACS Macro Lett., 2011, 1, 37.

    Article  Google Scholar 

  17. V. Guillerm,. J. Weselinśki, M. Alkordi, M. I. H. Mohideen, Y. Belmabkhout, A. J. Cairns, M. Eddaoudi, Chem. Commun., 2014, 50, 1937.

    Article  CAS  Google Scholar 

  18. Z. Xiang, D. Cao, W. Wang, W. Yang, B. Han, J. Lu, J. Phys. Chem. C, 2012, 116, 5974.

    Article  CAS  Google Scholar 

  19. D. B. Cordes, P. D. Lickiss, F. Rataboul, Chem. Rev., 2010, 110, 2081.

    Article  CAS  Google Scholar 

  20. Y. Zhu, W. Zhang, Chem. Sci., 2014, 5, 4957.

    Article  CAS  Google Scholar 

  21. R. M. Laine, M. F. Roll, Macromolecules, 2011, 44, 1073.

    Article  CAS  Google Scholar 

  22. E. O. Dare, L. K. Liu, J. Peng, Dalton Trans., 2006, 3668.

    Google Scholar 

  23. K. Kanamori, J. Mater. Res., 2014, 29, 2773.

    Article  CAS  Google Scholar 

  24. L. Guo, W. Wang, J. U. Otaigbe, J. Tissue Eng. Regen. Med., 2010, 4, 553.

    Article  CAS  Google Scholar 

  25. X. Jing, F. Sun, H. Ren, Y. Tian, M. Guo, L. Li, G. Zhu, Microporous Mesoporous Mater., 2013, 165, 92.

    Article  CAS  Google Scholar 

  26. J. J. Morrison, C. J. Love, B. W. Manson, I. J. Shannon, R. E. Morris, J. Mater. Chem., 2002, 12, 3208.

    Article  CAS  Google Scholar 

  27. W. Chaikittisilp, A. Sugawara, A. Shimojima, T. Okubo, Chem. Eur. J., 2010, 16, 6006.

    Article  CAS  Google Scholar 

  28. W. Chaikittisilp, A. Sugawara, A. Shimojima, T. Okubo, Chem. Mater., 2010, 22, 4841.

    Article  CAS  Google Scholar 

  29. D. Wang, L. Xue, L. Li, B. Deng, S. Feng, H. Liu, X. Zhao, Macromol. Rapid Commun., 2013, 34, 861.

    Article  Google Scholar 

  30. W. Chaikittisilp, M. Kubo, T. Moteki, A. Sugawara-Narutaki, A. Shimojima, T. Okubo, J. Am. Chem. Soc., 2011, 133, 13832.

    Article  CAS  Google Scholar 

  31. W. Yang, D. Wang, L. Li, H. Liu, Eur. J. Inorg. Chem., 2014, 2976.

    Google Scholar 

  32. Y. Qin, H. Ren, F. Zhu, L. Zhang, C. Shang, Z. Wei, M. Luo, Eur. Polym. J., 2011, 47, 853.

    Article  CAS  Google Scholar 

  33. N. Shanmugam, K. T. Lee, W. Y. Cheng, S. Y. Lu, J. Polym. Sci., Part A: Polym. Chem., 2012, 50, 2521.

    Article  CAS  Google Scholar 

  34. M. Roll, J. Kampf, Y. Kim, E. Yi, R. Laine, J. Am. Chem. Soc., 2010, 132, 10171.

    Article  CAS  Google Scholar 

  35. Y. Kim, K. Koh, M. F. Roll, R. M. Laine, A. J. Matzger, Macromolecules, 2010, 43, 6995.

    Article  CAS  Google Scholar 

  36. M. Winkler, L. M. de Espinosa, C. Barner-Kowollik, M. A. Meier, Chem. Sci., 2012, 3, 2607.

    Article  CAS  Google Scholar 

  37. A. Pogantsch, S. Rentenberger, G. Langer, J. Keplinger, W. Kern, E. Zojer, Adv. Funct. Mater., 2005, 15, 403.

    Article  CAS  Google Scholar 

  38. J. X. Jiang, F. Su, A. Trewin, C. D. Wood, N. L. Campbell, H. Niu, C. Dickinson, A. Y. Ganin, M. J. Rosseinsky, Y. Z. Khimyak, Angew. Chem., Int. Ed., 2007, 46, 8574.

    Article  CAS  Google Scholar 

  39. J.-X. Jiang, F. Su, A. Trewin, C. D. Wood, H. Niu, J. T. Jones, Y. Z. Khimyak, A. I. Cooper, J. Am. Chem. Soc., 2008, 130, 7710.

    Article  CAS  Google Scholar 

  40. P. Zhang, Z. Weng, J. Guo, C. Wang, Chem. Mater., 2011, 23, 5243.

    Article  CAS  Google Scholar 

  41. V. Borisenko, D. C. Burns, Z. Zhang, G. A. Woolley, J. Am. Chem. Soc., 2000, 122, 6364.

    Article  CAS  Google Scholar 

  42. N. Liu, Z. Chen, D. R. Dunphy, Y. B. Jiang, R. A. Assink, C. J. Brinker, Angew. Chem., Int. Ed., 2003, 42, 1731.

    Article  CAS  Google Scholar 

  43. N. Li, J. Lu, Q. Xu, L. Wang, Opt. Mater., 2006, 28, 1412.

    Article  CAS  Google Scholar 

  44. A. A. Beharry, G. A. Woolley, Chem. Soc. Rev., 2011, 40, 4422.

    Article  CAS  Google Scholar 

  45. M. Petr, P. T. Hammond, Macromolecules, 2011, 44, 8880.

    Article  CAS  Google Scholar 

  46. H. A. Patel, S. H. Je, J. Park, D. P. Chen, Y. Jung, C. T. Yavuz, A. Coskun, Nat. Commun., 2013, 4, 1357.

    Article  Google Scholar 

  47. H. Nishioka, X. Liang, H. Kashida, H. Asanuma, Chem. Commun., 2007, 4354.

    Google Scholar 

  48. T. Chen, S. Xu, F. Zhang, D. G. Evans, X. Duan, Chem. Eng. Sci., 2009, 64, 4350.

    Article  CAS  Google Scholar 

  49. H. Chi, K. Y. Mya, T. Lin, C. He, F. Wang, W. S. Chin, New J. Chem., 2013, 37, 735.

    Article  CAS  Google Scholar 

  50. Y. Liu, W. Yang, H. Liu, Chem. Eur. J., 2015, 21, 4731.

    Article  CAS  Google Scholar 

  51. D. Chen, S. Yi, W. Wu, Y. Zhong, J. Liao, C. Huang, W. Shi, Polymer, 2010, 51, 3867.

    Article  CAS  Google Scholar 

  52. W. Zhang, K. Yoshida, M. Fujiki, X. Zhu, Macromolecules, 2011, 44, 5105.

    Article  CAS  Google Scholar 

  53. R. H. Baney, M. Itoh, A. Sakakibara, T. Suzuki, Chem. Rev., 1995, 95, 1409.

    Article  CAS  Google Scholar 

  54. S. Guo, A. Sugawara-Narutaki, T. Okubo, A. Shimojima, J. Mater. Chem. C, 2013, 1, 6989.

    Article  CAS  Google Scholar 

  55. G. Cheng, N. R. Vautravers, R. E. Morris, D. J. Cole-Hamilton, Org. Biomol. Chem., 2008, 6, 4662.

    Article  CAS  Google Scholar 

  56. K. S. Sing, Pure Appl. Chem., 1985, 57, 603.

    Article  CAS  Google Scholar 

  57. M. Rose, N. Klein, W. Böhlmann, B. Böhringer, S. Fichtner, S. Kaskel, Soft Matter, 2010, 6, 3918.

    Article  CAS  Google Scholar 

  58. Y. Peng, T. Ben, J. Xu, M. Xue, X. Jing, F. Deng, S. Qiu, G. Zhu, Dalton Trans., 2011, 40, 2720.

    Article  CAS  Google Scholar 

  59. S. Wang, L. Tan, C. Zhang, I. Hussain, B. Tan, J. Mater. Chem. A, 2015, 3, 6542.

    Article  CAS  Google Scholar 

  60. K. Rameshbabu, P. Kannan, Polym. Int., 2006, 55, 151.

    Article  CAS  Google Scholar 

  61. S. Choi, J. H. Drese, C. W. Jones, ChemSusChem, 2009, 2, 796.

    Article  CAS  Google Scholar 

  62. Q. Chen, D. P. Liu, M. Luo, L. J. Feng, Y. C. Zhao, B. H. Han, Small, 2014, 10, 308.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People’s Republic of China

    Chundong Jiang & Hongzhi Liu

  2. State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai, 200433, People’s Republic of China

    Wenyan Yang & Hongzhi Liu

Authors
  1. Chundong Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wenyan Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hongzhi Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hongzhi Liu.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 1076—1085, April, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jiang, C., Yang, W. & Liu, H. Hybrid azobenzene-doped nanoporous polymers derived from cubic octavinylsilsesquioxane. Russ Chem Bull 65, 1076–1085 (2016). https://doi.org/10.1007/s11172-016-1416-x

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-016-1416-x

Keywords

Search

Navigation