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Asymmetric hydrogenation of 3-methylbenz[b][1,4]oxazin-2-ones catalyzed by iridium complexes with phosphite-type ligands

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Abstract

The chiral amidophosphite ligand in the iridium-catalyzed hydrogenation of 3-methylbenz[b][1,4]oxazin-2-ones in ethanol provides higher conversion and enantioselectivity than the phosphite ligand.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. E. Lyubimov, D. B. Ozolin & V. A. Davankov

Authors
  1. A. E. Lyubimov
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  2. D. B. Ozolin
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  3. V. A. Davankov
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Correspondence to A. E. Lyubimov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0828—0830, March, 2016.

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Lyubimov, A.E., Ozolin, D.B. & Davankov, V.A. Asymmetric hydrogenation of 3-methylbenz[b][1,4]oxazin-2-ones catalyzed by iridium complexes with phosphite-type ligands. Russ Chem Bull 65, 828–830 (2016). https://doi.org/10.1007/s11172-016-1384-1

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  • DOI: https://doi.org/10.1007/s11172-016-1384-1

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