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Photoinduced excimer formation of boron difluoride β-diketonates in poly(methyl methacrylate)

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Abstract

The photochemical behavior of β-diketonates of boron difluoride in poly(methyl methacrylate) was studied. Excimers of boron chelates are formed in the course of UV irradiation of polymer compositions accompanied by a bathochromic shift of the luminescence spectrum. The intensification (quenching) of luminescence of the polymer compositions during irradiation depends on the ratio of the quantum yields of the monomer and excimer luminescence of boron difluoride β-diketonates.

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Authors and Affiliations

  1. Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    A. G. Mirochnik, E. V. Fedorenko & D. Kh. Shlyk

Authors
  1. A. G. Mirochnik
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  2. E. V. Fedorenko
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  3. D. Kh. Shlyk
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Correspondence to A. G. Mirochnik.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0806—0810, March, 2016.

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Mirochnik, A.G., Fedorenko, E.V. & Shlyk, D.K. Photoinduced excimer formation of boron difluoride β-diketonates in poly(methyl methacrylate). Russ Chem Bull 65, 806–810 (2016). https://doi.org/10.1007/s11172-016-1378-z

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  • DOI: https://doi.org/10.1007/s11172-016-1378-z

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