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A new access to azabicyclo[4.3.0]nonane alkaloids

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Abstract

A new approach towards 3-azabicyclo[4.3.0]nonane alkaloids was implemented an intramolecular [3+2] cycloaddition of silyl nitronate generated from (L)-(−)-linalool nitro derivative, (3R,6RS)-3-acetoxy-3,7-dimethyl-6-nitro-1,7-octadiene, as a key step in the synthetic scheme.

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Correspondence to V. V. Veselovsky.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0741—0747, March, 2016.

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Lozanova, A.V., Stepanov, A.V. & Veselovsky, V.V. A new access to azabicyclo[4.3.0]nonane alkaloids. Russ Chem Bull 65, 741–747 (2016). https://doi.org/10.1007/s11172-016-1366-3

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  • DOI: https://doi.org/10.1007/s11172-016-1366-3

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