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Sonoluminescence and sonochemiluminescence of peroxide solutions

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Abstract

Two sonochemiluminescence mechanisms were established in peroxide solutions. The sonochemiluminescence intensity often exceeds the sonoluminescence intensity of solvents caused by inelastic collisions of cavitation bubbles in the gas phase. In solutions of peroxides, whose chemiluminescence decomposition proceeds via the monomolecular peroxide decomposition involving no radical intermediates with a high activation energy, in particular, for adamantylidenadamantane-1,2-dioxetane, the mechanism based on the total thermal ultrasonic action on the solution takes place. The initiation of chemiluminescence reactions of peroxide decomposition by radical products of solvent sonolysis is a source of sonochemiluminescence for peroxides decomposing via the radical mechanism, for example, for cumene peroxide.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    G. L. Sharipov, A. M. Abdrakhmanov, L. R. Yakshembetova & A. A. Tukhbatullin

  2. Institute of Physics and Technology, Mongolian Academy of Sciences, 54b Peace av., 13330, Ulaanbaatar, Mongolia

    R. Khoroljav

Authors
  1. G. L. Sharipov
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  2. A. M. Abdrakhmanov
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  3. R. Khoroljav
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  4. L. R. Yakshembetova
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  5. A. A. Tukhbatullin
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Correspondence to G. L. Sharipov.

Additional information

Based on materials of the XXVI Conference “Modern Chemical Physics” (September 20—October 1, 2014, Tuapse, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0167—0172, January, 2016.

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Sharipov, G.L., Abdrakhmanov, A.M., Khoroljav, R. et al. Sonoluminescence and sonochemiluminescence of peroxide solutions. Russ Chem Bull 65, 167–172 (2016). https://doi.org/10.1007/s11172-016-1279-1

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  • DOI: https://doi.org/10.1007/s11172-016-1279-1

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