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Encapsulation of quantum dots in supramolecular systems based on amphiphilic compounds and polyelectrolytes

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Abstract

Supramolecular nanocontainers based on monocationic and gemini surfactants and oppositely charged polyelectrolytes (polyacrylic acid, polyethyleneimine) for the stabilization and enhancement of solubility of hydrophobic quantum dots CdSe/ZnS were formed. The size (from 2 to 70 nm depending on the type of nanocontainers) and shape of aggregates containing quantum dots were determined by transmission electron microscopy. It was shown that the nature of the stabilizing agent influences the morphology of aggregates. The increase in photostability of quantum dots in micellar solutions of gemini surfactants and the possibility of their preservation in the polyelectrolyte capsules are identified.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    G. A. Gaynanova, E. A. Vasilieva, I. R. Nizameev, M. K. Kadirov, L. Ya. Zakharova & A. I. Konovalov

  2. Kazan National Research Technological University, 68 ul. K. Marksa, 420015, Kazan, Russian Federation

    G. A. Gaynanova, E. A. Vasilieva, A. M. Bekmukhametova, I. R. Nizameev, M. K. Kadirov & L. Ya. Zakharova

Authors
  1. G. A. Gaynanova
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  2. E. A. Vasilieva
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  3. A. M. Bekmukhametova
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  4. I. R. Nizameev
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  5. M. K. Kadirov
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  6. L. Ya. Zakharova
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  7. A. I. Konovalov
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Corresponding author

Correspondence to G. A. Gaynanova.

Additional information

Dedicated to Academician of the Russian Academy of Sciences N. S. Zefirov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0151—0157, January, 2016.

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Gaynanova, G.A., Vasilieva, E.A., Bekmukhametova, A.M. et al. Encapsulation of quantum dots in supramolecular systems based on amphiphilic compounds and polyelectrolytes. Russ Chem Bull 65, 151–157 (2016). https://doi.org/10.1007/s11172-016-1277-3

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  • DOI: https://doi.org/10.1007/s11172-016-1277-3

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