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Synthesis and reactivity of metal-containing monomers 76. Nanostructured materials obtained by controlled thermolysis of Ni, Co, and Cu chelate complexes with azomethine ligands

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Abstract

The controlled thermolysis of mono(NiII, CuII, and CoII) and dinuclear (NiII, CuII, and FeII) chelate complexes with azomethine ligands, containing oxygen, nitrogen, and sulfur atoms in the chelate rings, was studied. The effect of the ligand environment on the thermal stability and composition of the resulting nanocomposites was examined. Comparative thermal analysis (DSC, DTA, and TGA) of the metal chelate complexes was performed. Their thermolysis products were characterized using elemental analysis, X-ray powder diffraction, scanning electron microscopy, and gel permeation chromatography. The magnetic properties of the nanocomposites obtained were analyzed.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. D. Pomogailo, G. I. Dzhardimalieva, S. I. Pomogailo, N. D. Golubeva, G. V. Shilov & E. A. Dzhavadyan

  2. Research Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    A. S. Burlov & S. A. Mashchenko

  3. Southern Scientific Center, 41 ul. Chekhova, 344006, Rostov-on-Don, Russian Federation

    D. A. Garnovskii

Authors
  1. A. D. Pomogailo
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  2. G. I. Dzhardimalieva
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  3. S. I. Pomogailo
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  4. N. D. Golubeva
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  5. G. V. Shilov
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  6. E. A. Dzhavadyan
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  7. A. S. Burlov
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  8. S. A. Mashchenko
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  9. D. A. Garnovskii
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Corresponding author

Correspondence to G. I. Dzhardimalieva.

Additional information

For Part 75, see Ref. 1.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0139—0150, January, 2016.

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Pomogailo, A.D., Dzhardimalieva, G.I., Pomogailo, S.I. et al. Synthesis and reactivity of metal-containing monomers 76. Nanostructured materials obtained by controlled thermolysis of Ni, Co, and Cu chelate complexes with azomethine ligands. Russ Chem Bull 65, 139–150 (2016). https://doi.org/10.1007/s11172-016-1276-4

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  • DOI: https://doi.org/10.1007/s11172-016-1276-4

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