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Potassium carbonate as a base for generation of carbanions from CH-acids in organic synthesis

Russian Chemical Bulletin volume 65, pages 14–28 (2016)Cite this article

Abstract

A reaction of CH-acids with electrophilic agent (Michael acceptors, alkyl and allyl halides, dihaloalkanes and -alkenes, etc.) in the presence of potassium carbonate constitutes a convenient method for the elongation of the carbon chain and provides a possibility to develop preparative methods for the preparation of both the linear and the cyclic structures.

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  1. Institute of Chemical Reactants and Ultrapure Compounds (IREA), 3 Bogorodskii val, 107076, Moscow, Russian Federation

    D. S. Khachatryan

  2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    K. R. Matevosyan

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  1. D. S. Khachatryan
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0014—0028, January, 2016.

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Khachatryan, D.S., Matevosyan, K.R. Potassium carbonate as a base for generation of carbanions from CH-acids in organic synthesis. Russ Chem Bull 65, 14–28 (2016). https://doi.org/10.1007/s11172-016-1260-z

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