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Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer

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Abstract

A metal-organic coordination polymer of the formula [Li3(btc)(H2O)] (1a) (H3btc is the trimesic acid, C6H3(COOH)3) was obtained upon heating a mixture of LiBH4 and H3btc in ethanol. The structure was established by single crystal X-ray diffraction study. The studies by TGA show that polymer 1a loses the coordinated water at T ≥ 250 °C, whereas the metal-organic framework of lithium trimesate disintegrates only above 500 °C. The luminescence spectra showed a considerable (5-fold) increase in luminescence intensity and a bathochromic shift upon dehydration of 1a.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent´eva, 630090, Novosibirsk, Russian Federation

    T. K. Koltunova, D. G. Samsonenko, M. I. Rakhmanova, D. N. Dybtsev & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

Authors
  1. T. K. Koltunova
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  2. D. G. Samsonenko
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  3. M. I. Rakhmanova
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  4. D. N. Dybtsev
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  5. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2903—2907, December, 2015.

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Koltunova, T.K., Samsonenko, D.G., Rakhmanova, M.I. et al. Synthesis, crystal structure, thermal stability, and luminescent properties of lithium trimesate coordination polymer. Russ Chem Bull 64, 2903–2907 (2015). https://doi.org/10.1007/s11172-015-1245-3

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  • DOI: https://doi.org/10.1007/s11172-015-1245-3

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