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Synthesis of [(N-acetyl-N-methyl)aminomethyl](dimethyl)silyl nitrate

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Abstract

Transsilylation of N-methyl-N-trimethylsilylacetamide with chloromethyl(dimethyl)silylnitrate ClCH2SiMe2ONO2 led to the formation of (N-acetyl-N-methyl)aminomethyl](dimethyl)silyl nitrate, the (O–Si)-chelate with the intramolecular coordination C=O→Si bond. Spectral characteristics of this compound and the reaction product of N-[chloro(dimethyl)silylmethyl]-N-methylacetamide with silver nitrate are identical.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    N. F. Lazareva, V. V. Belyaeva & I. M. Lazarev

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  1. N. F. Lazareva
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  2. V. V. Belyaeva
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  3. I. M. Lazarev
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Correspondence to N. F. Lazareva.

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Dedicated to Academician of the Russian Academy of Sciences N. S. Zefirov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2265–2268, September, 2015.

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Lazareva, N.F., Belyaeva, V.V. & Lazarev, I.M. Synthesis of [(N-acetyl-N-methyl)aminomethyl](dimethyl)silyl nitrate. Russ Chem Bull 64, 2265–2268 (2015). https://doi.org/10.1007/s11172-015-1150-9

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  • DOI: https://doi.org/10.1007/s11172-015-1150-9

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