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Unusual reaction of triazole derivatives with 1-iodomethyl-1,1,3,3,3-pentamethyldisiloxane

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Abstract

The solvent-free reaction of 1-iodomethyl-1,1,3,3,3-pentamethyldisiloxane with 1,2,4-triazole derivatives and 1,2,3-benzotriazole afforded organylcyclosiloxane iodides and triiodides. The reactions involved alkylation of pyridine and pyrrole nitrogens and cleavage of the siloxane bonds mediated by hydrogen iodide generated upon the reaction.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    L. G. Shagun, I. A. Dorofeev, L. V. Zhilitskaya, N. O. Yarosh & L. I. Larina

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  1. L. G. Shagun
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  2. I. A. Dorofeev
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  3. L. V. Zhilitskaya
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  4. N. O. Yarosh
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  5. L. I. Larina
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Correspondence to L. G. Shagun.

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Dedicated to Academician of the Russian Academy of Sciences N. S. Zefirov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2261–2264, September, 2015.

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Shagun, L.G., Dorofeev, I.A., Zhilitskaya, L.V. et al. Unusual reaction of triazole derivatives with 1-iodomethyl-1,1,3,3,3-pentamethyldisiloxane. Russ Chem Bull 64, 2261–2264 (2015). https://doi.org/10.1007/s11172-015-1149-2

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  • DOI: https://doi.org/10.1007/s11172-015-1149-2

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