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Reactions of 2-aminothiophenol with pyridineand imidazolecarboxaldehydes

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Abstract

Reflux of imidazole-2-carboxaldehyde, 1-methylimidazole-2-carboxaldehyde, imidazole4-carboxaldehyde, or 5-bromopyridine-2-carboxaldehyde with 2-aminothiophenol in ethanol in the presence of air oxygen for 1.5 h affords the corresponding 2-hetaryl-substituted 1,3-benzothiazoles. The reaction of 2-(1-methyl-1H-imidazol-2-yl)-1,3-benzothiazole with Cu(ClO4)2•6H2O gives bis[2-(1-methyl-1H-imidazol-2-yl)-1,3-benzothiazole]copper(ii) diperchlorate monohydrate.

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Authors and Affiliations

  1. Chemistry Department, M. V. Lomonosov Moscow State University, 1/3 Leninskie Gory, 119991, Moscow, Russian Federation

    E. S. Barskaya, E. K. Beloglazkina, A. G. Mazhuga, I. V. Yudin & N. V. Zyk

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  1. E. S. Barskaya
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  2. E. K. Beloglazkina
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  3. A. G. Mazhuga
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  4. I. V. Yudin
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  5. N. V. Zyk
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Corresponding author

Correspondence to E. K. Beloglazkina.

Additional information

Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1975—1977, August, 2015.

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Barskaya, E.S., Beloglazkina, E.K., Mazhuga, A.G. et al. Reactions of 2-aminothiophenol with pyridineand imidazolecarboxaldehydes. Russ Chem Bull 64, 1975–1977 (2015). https://doi.org/10.1007/s11172-015-1103-3

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  • DOI: https://doi.org/10.1007/s11172-015-1103-3

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