Abstract
New norbornene monomer, viz., 5-[(bicyclo[2.2.1]hept-5-en-2-ylmethoxy)methyl]-8-[(dimesitylboryl)oxy]quinoline (1), was synthesized. The copolymers based on monomer 1 and carbazole-containing norbornene derivatives were synthesized by ring-opening metathesis polymerization. The photoluminescent (PL) and electroluminescent (EL) properties of the synthesized polymeric products were studied. The copolymers revealed the green EL with a maximum luminance of 146 cd m–2. The dependences between the PL and EL efficiencies of the polymers and their structures were determined.
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Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1949—1954, August, 2015.
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Rozhkov, A.V., Basova, G.V., Korshunov, A.O. et al. Synthesis and luminescent properties of functionalized polynorbornenes with boron-containing fragments in side chains. Russ Chem Bull 64, 1949–1954 (2015). https://doi.org/10.1007/s11172-015-1098-9
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DOI: https://doi.org/10.1007/s11172-015-1098-9