Abstract
Erbium(iii)—HEDP and erbium(iii)—calcium(ii)—HEDP systems (HEDP is 1-hydroxyethylidene-1,1-diphosphonic acid) have been studied using potentiometry method in association with mathematical modelling. In the erbium(iii)—HEDP system the formation of compexes having various degree of deprotonation of a ligand, 1 : 1 and 2 : 1 monoand dinuclear complexes, as well as mononuclear bis-complexes has been shown. It was found, that heteronuclear complexes generated in erbium(iii)—calcium(ii)—HEDP system, do not coincide neither with calcium nor with erbium forms in composition.
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Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1866—1870, August, 2015.
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Devyatov, F.V., Musin, D.R. Study of homo- and heteronuclear complex formation in 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP)—erbium(iii) and HEDP—erbium(iii)—calcium(ii) systems in an aqueous solution. Russ Chem Bull 64, 1866–1870 (2015). https://doi.org/10.1007/s11172-015-1085-1
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DOI: https://doi.org/10.1007/s11172-015-1085-1