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Spectroscopic methods as instruments for the prediction of catalytic behavior of metal-organic frameworks

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Abstract

The results of the studies of the acid-base and catalytic properties of metal-organic frameworks (MOFs) are generalized. Significant attention is given to possibilities of spectral methods (IR and ESR) for the study of the nature of acid-base sites and determination of the character of their interaction with organic molecules. The influence has been analyzed of the nature of these sites and structural factors on the catalytic properties of MOFs in reactions of the acid-base type. The presented results demonstrate the possibility of using spectroscopic data for the understanding of the nature and specificity of the catalytic effect of MOFs at the atomic molecular level and for the prediction of their catalytic properties.

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References

  1. G. Ferey, J. Solid State Chem., 2000, 152, 37.

    Article  CAS  Google Scholar 

  2. G. Ferey, Chem. Soc. Rev., 2008, 37, 191.

    Article  CAS  Google Scholar 

  3. M. L. Foo, R. Matsuda, S. Kitagawa, Chem. Mater., 2014, 26, 310.

    Article  CAS  Google Scholar 

  4. M. O´Keeffe, M. Eddaoudi, H. Li, J. Solid State Chem., 2000, 152, 3.

    Article  Google Scholar 

  5. H. Li, M. Eddaoudi, M. O´Keeffe, O. M. Yaghi, Nature, 1999, 402, 276.

    Article  CAS  Google Scholar 

  6. J. Gascon, A. Corma, F. Kapteijn, F. X. Llabres i Xamena, ACS Catal., 2014, 4, 361.

    Article  CAS  Google Scholar 

  7. M. N. Timofeeva, V. N. Panchenko, A. A. Abel, Nazmul Abedin Khan, Imteaz Ahmed, A. B. Ayupov, K. P. Volcho, Sung Hwa Jhung, J. Catal., 2014, 311, 114.

    Article  CAS  Google Scholar 

  8. M. N. Timofeeva, V. N. Panchenko, J. W. Jun, Z. Hasan, M. M. Matrosova, S. H. Jhung, Appl. Catal. A: Gen., 2014, 471, 91.

    Article  CAS  Google Scholar 

  9. V. N. Panchenko, M. M. Matrosova, Jaewoo Jeon, Jong W. Jun, M. N. Timofeeva, S. H. Jhung, J. Catal., 2014, 316, 251.

    Article  CAS  Google Scholar 

  10. M. M. Matrosova, V. N. Panchenko, M. N. Timofeeva, S. H. Jhung, International Workshop on Transition Metal Clusters, IWTMC–IV (September 8—11, 2014), Novosibirsk, Russia.

  11. E. A. Paukshtis, Infrakrasnaya spektroskopiya v geterogennom kislotno-osnovnom katalize [IR Spectroscopy in Heterogeneous Acid-Base Catalysis], Nauka, Novosibirsk, 1992, p. 255 (in Russian).

    Google Scholar 

  12. E. A. Paukshtis, E. N. Yurchenko, Usp. Khim., 1983, 52, 426 [Russ. Chem. Rev. (Engl. Transl.), 1983, 52].

    Article  Google Scholar 

  13. A. A. Davydov, Molecular Spectroscopy of Oxide Catalyst Surfaces, Wiley, England, 2003.

    Book  Google Scholar 

  14. J. A. Rabo, G. J. Gajda, Catal. Rev.-Sci. Eng., 1989, 31, 385.

    Article  CAS  Google Scholar 

  15. M. N. Timofeeva, V. N. Panchenko, Z. Hasan, S. H. Jhung, Appl. Catal. A: Gen., 2013, 455, 71.

    Article  CAS  Google Scholar 

  16. C. Lamberti, A. Zecchina, E. Groppo, S. Bordiga, Chem. Soc. Rev., 2010, 39, 4951.

    Article  CAS  Google Scholar 

  17. A. Vimont, F. Thibault-Starzyk, M. Daturi, Chem. Soc. Rev., 2010, 39, 4928.

    Article  CAS  Google Scholar 

  18. A. Dhakshinamoorthy, M. Alvaro, H. Garcia, Chem. Commun., 2012, 48, 11275.

    Article  CAS  Google Scholar 

  19. J. J. Low, A. I. Benin, P. Jakubczak, J. F. Abrahamian, S. A. Faheem, R. R. Willis, J. Am. Chem. Soc., 2009, 131, 15834.

    Article  CAS  Google Scholar 

  20. E. Perez-Mayoral, Z. Musilova, B. Gil, B. Marszalek, M. Položij, P. Nachtigall, J. Cejka, Dalton Trans., 2012, 41, 4036.

    Article  CAS  Google Scholar 

  21. A. Vimont, H. Leclerc, F. Mauge, M. Daturi, J. C. Lavalley, S. Surble, C. Serre, G. Ferey, J. Phys. Chem. C, 2007, 111, 383.

    Article  CAS  Google Scholar 

  22. Y. K. Hwang, D. Y. Hong, J. S. Chang, S. H. Jhung, Y. K. Seo, J. Kim, A. Vimont, M. Daturi, C. Serre, G. Ferey, Angew. Chem., Int. Ed., 2008, 47, 4144.

    Article  CAS  Google Scholar 

  23. J. W. Yoon, Y.-K. Seo, Y. K. Hwang, J.-S. Chang, H. Leclerc, S. Wuttke, P. Bazin, A. Vimont, M. Daturi, E. Bloch, P. L. Llewellyn, C. Serre, P. Horcajada, J.-M. Greneche, A. E. Rodrigues, G. Ferey, Angew. Chem., Int. Ed., 2010, 49, 5949.

    Article  CAS  Google Scholar 

  24. C. Lamberti, A. Zecchina, E. Groppo, S. Bordiga, Chem. Soc. Rev., 2010, 39, 4951.

    Article  CAS  Google Scholar 

  25. A. Dhakshinamoorthy, M. Alvaro, P. Horcajada, E. Gibson, M. Vishnuvarthan, A. Vimont, J.-M. Greneche, C. Serre, M. Daturi, H. Garcia, ACS Catal., 2012, 2, 2060.

    Article  CAS  Google Scholar 

  26. A. C. McKinlay, J. F. Eubank, S. Wuttke, B. Xiao, P. S. Wheatley, P. Bazin, J.-C. Lavalley, M. Daturi, A. Vimont, G. De Weireld, P. Horcajada, C. Serre, R. E. Morris, Chem. Mater., 2013, 25, 1592.

    Article  CAS  Google Scholar 

  27. S. Bordiga, L. Regli, F. Bonino, E. Groppo, C. Lamberti, B. Xiao, P. S. Wheatley, R. E. Morris, A. Zecchina, Phys. Chem. Chem. Phys., 2007, 9, 2676.

    Article  CAS  Google Scholar 

  28. H. Leclerc, A. Vimont, J.-C. Lavalley, M. Daturi, A. D. Wiersum, P. L. Llwellyn, P. Horcajada, G. Ferey, C. Serre, Phys. Chem. Chem. Phys., 2011, 13, 11748.

    Article  CAS  Google Scholar 

  29. C. Volkringer, H. Leclerc, J.-C. Lavalley, T. Loiseau, G. Ferey, M. Daturi, A. Vimont, J. Phys. Chem. C, 2012, 116, 5710.

    Article  CAS  Google Scholar 

  30. A. Vimont, J. M. Goupil, J. C. Lavalley, M. Daturi, S. Surble, C. Serre, F. Millange, G. Ferey, N. Audebrand, J. Am. Chem. Soc., 2006, 128, 3218.

    Article  CAS  Google Scholar 

  31. L. N. Ikryannikova, G. L. Markaryan, A. N. Kharlanov, E. V. Lunina, Appl. Surf. Sci., 2003, 207, 100.

    Article  CAS  Google Scholar 

  32. E. V. Lunina, G. L. Markaryan, O. O. Parenago, A. V. Fionov, Colloids Surf. A: Physicochem. Eng. Aspects, 1993, 72, 333.

    Article  CAS  Google Scholar 

  33. M. N. Timofeeva, V. N. Panchenko, A. Gil, V. P. Doronin, A. V. Golovin, A. S. Andreev, V. A. Likholobov, Appl. Catal. B: Environ., 2011, 104, 54.

    Article  CAS  Google Scholar 

  34. M. N. Timofeeva, V. N. Panchenko, Z. Hasan, N. A. Khan, M. S. Mel´gunov, A. A. Abel, M. M. Matrosova, K. P. Volcho, S. H. Jhung, Appl. Catal. A: Gen., 2014, 469, 427.

    Article  CAS  Google Scholar 

  35. T. Montanari, M. Bevilacqua, C. Resini, G. Busca, J. Phys. Chem. B, 2004, 108, 2120.

    Article  CAS  Google Scholar 

  36. L. Hammett, J. Am. Chem. Soc., 1937, 59, 96.

    Article  CAS  Google Scholar 

  37. K. Tanabe, Solid Acids and Bases. Academic Press, New York—London, 1970.

    Book  Google Scholar 

  38. J. Portier, G. Campet, J. Etourneau, M. C. R. Shastry, B. Tanguy, J. Alloys Compounds, 1994, 209, 59.

    Article  CAS  Google Scholar 

  39. C. Volkringer, D. Popov, T. Loiseau, G. Ferey, M. Burghammer, C. Riekel, M. Haouas, F. Taulelle, Chem. Mater., 2009, 21, 5695.

    Article  CAS  Google Scholar 

  40. S. S.-Y. Chui, S. M.-F. Lo, J. P. H. Charmant, A. Orpen, I. D. Williams, Science, 1999, 283, 1148.

    Article  CAS  Google Scholar 

  41. L. Valenzano, B. Civalleri, S. Chavan, S. Bordiga, M. H. Nilsen, S. Jakobsen, K. P. Lillerud, C. Lamberti, Chem. Mater., 2011, 23, 1700.

    Article  CAS  Google Scholar 

  42. J. Gascon, A. Corma, F. Kapteijn, F. X. Llabrés i Xamena, ACS Catal., 2014, 4, 361.

    Article  CAS  Google Scholar 

  43. L. Alaerts, E. Seguin, H. Poelman, F. Thibault-Starzyk, P. A. Jacobs, D. E. De Vos, Chem. Eur. J., 2006, 12, 7353.

    Article  CAS  Google Scholar 

  44. J. Kaminska, M. A. Schwegler, A. J. Hoefnagel, H. van Bekkum, Recl. Trav. Chim. Pays-Bas, 1992, 111, 432.

    Article  CAS  Google Scholar 

  45. A. Dhakshinamoorthy, M. Alvaro, H. Chevreau, P. A. Horcajada, T. Devic, C. Serre, H. Garcia, Catal. Sci. Technol., 2012, 2, 324.

    Article  CAS  Google Scholar 

  46. M. Opanasenko, A. Dhakshinamoorthy, M. Shamzhy, P. Nachtigall, M. Horacek, H. Garcia, J. Cejka, Catal. Sci. Technol., 2013, 3, 500.

    Article  CAS  Google Scholar 

  47. A. Dhakshinamoorthy, M. Alvaro, H. Garcia, Adv. Synth. Catal., 2010, 352, 3022.

    Article  CAS  Google Scholar 

  48. A. Herbst, A. Khutia, C. Janiak, Inorg. Chem., 2014, 53, 7319.

    Article  CAS  Google Scholar 

  49. A. Dhakshinamoorthy, M. Alvaro, P. Horcajada, E. Gibson, M. Vishnuvarthan, A. Vimont, J.-M. Greneche, C. Serre, M. Daturi, H. Garcia, ACS Catal., 2012, 2, 2060.

    Article  CAS  Google Scholar 

  50. M. Opanasenko, A. Dhakshinamoorthy, M. Shamzhy, P. Nachtigall, M. Horacek, H. Garciaca, Catal. Sci. Technol., 2013, 3, 500.

    Article  CAS  Google Scholar 

  51. F. Vermoortele, M. Vandichel, B. V. de Voorde, R. Ameloot, M. Waroquier, V. Van Speybroeck, D. E. De Vos, Angew. Chem., Int. Ed., 2012, 51, 4887.

    Article  CAS  Google Scholar 

  52. Y. Yang, H.-F. Yao, F.-G. Xi, E.-Q. Gao, J. Mol. Catal. A: Chem., 2014, 390, 198.

    Article  CAS  Google Scholar 

  53. M. Hartmann, M. Fischer, Micropor. Mesopor. Mater., 2012, 164, 38.

    Article  CAS  Google Scholar 

  54. R. Cortese, D. Duca, Phys. Chem. Chem. Phys., 2011, 13, 1599.

    Article  Google Scholar 

  55. J. Gascon, U. Aktay, M. D. Hernandez-Alonso, G. P. M. van Klink, F. Kapteijn, J. Catal., 2009, 261, 75.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent´eva, 630090, Novosibirsk, Russian Federation

    V. N. Panchenko & M. N. Timofeeva

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    V. N. Panchenko & M. N. Timofeeva

  3. Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu, 702-701, Republic of Korea

    Sung Hwa Jhung

  4. Novosibirsk State Technical University, 20 prosp. K. Marksa, 630092, Novosibirsk, Russian Federation

    M. N. Timofeeva

Authors
  1. V. N. Panchenko
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  2. Sung Hwa Jhung
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  3. M. N. Timofeeva
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Correspondence to V. N. Panchenko.

Additional information

Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1772—1783, August, 2015.

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Panchenko, V.N., Jhung, S.H. & Timofeeva, M.N. Spectroscopic methods as instruments for the prediction of catalytic behavior of metal-organic frameworks. Russ Chem Bull 64, 1772–1783 (2015). https://doi.org/10.1007/s11172-015-1071-7

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  • DOI: https://doi.org/10.1007/s11172-015-1071-7

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