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Aggregation state of amphiphilic cationic tetraphenylporphyrin derivatives in aqueous microheterogeneous systems

Russian Chemical Bulletin volume 64, pages 806–811 (2015)Cite this article

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Abstract

The conditions for the formation of ionic associates and J- and H-aggregates from amphiphilic cationic tetraphenylporphyrin derivatives in aqueous solutions of anionic surfactants and polyelectrolytes in a wide range of concentrations and pH are considered. The aggregation behaviors of tetraphenylporphyrin and its cationic derivatives in aqueous microheterogeneous systems are compared illustrating the influence of the porphyrin molecular structure on its ability to form supramolecular aggregates of a certain structure. The mechanism of the promoting action of premicellar solutions of anionic surfactants on the formation of J-aggregates of the diprotonated form of cationic porphyrins was proposed. The acid-base properties of a number of new synthetic meso-aryl-substituted porphyrins in aqueous microheterogeneous systems were characterized.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    M. A. Gradova & A. V. Lobanov

  2. M. V. Lomonosov Moscow State University of Fine Chemical Technologies, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    K. A. Zhdanova & N. A. Bragina

  3. M. V. Lomonosov Moscow State University, 1/3 Leninskie Gory, 119991, Moscow, Russian Federation

    M. Ya. Mel´nikov

Authors
  1. M. A. Gradova
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  2. K. A. Zhdanova
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  3. N. A. Bragina
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  4. A. V. Lobanov
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  5. M. Ya. Mel´nikov
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Correspondence to M. A. Gradova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0806–0811, April, 2015.

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Gradova, M.A., Zhdanova, K.A., Bragina, N.A. et al. Aggregation state of amphiphilic cationic tetraphenylporphyrin derivatives in aqueous microheterogeneous systems. Russ Chem Bull 64, 806–811 (2015). https://doi.org/10.1007/s11172-015-0937-z

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  • DOI: https://doi.org/10.1007/s11172-015-0937-z

Key words

  • tetraphenylporphyrin
  • cationic porphyrins
  • J-aggregates
  • porphyrin—surfactant complexes
  • premicellar aggregates
  • anionic surfactants
  • polyelectrolytes
  • microheterogeneous systems