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NMR study of reactions of organyltrichlorophosphonium hexachlorophosphorates with triethylamine

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Abstract

The reactions of trichloro(2-ethoxyethenyl)phosphonium and trichloro(styryl)phosphonium hexachlorophosphorates with triethylamine were studied by 1H, 13C, and 31P NMR spectroscopy. It was shown that phosphonyl chlorides are the primary products of the reactions. The presence of the alkoxy group in hexachlorophosphorate results in the oxidation of the PCl2 group to form phosphonyl chlorides. Diphosphorylated oxaphosphinines were synthesized.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    L. I. Larina & T. N. Komarova

  2. Irkutsk State University, 1 ul. Karla Marksa, 664003, Irkutsk, Russian Federation

    V. G. Rozinov

Authors
  1. L. I. Larina
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  2. T. N. Komarova
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  3. V. G. Rozinov
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Correspondence to L. I. Larina.

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Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0732—0737, March, 2015.

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Larina, L.I., Komarova, T.N. & Rozinov, V.G. NMR study of reactions of organyltrichlorophosphonium hexachlorophosphorates with triethylamine. Russ Chem Bull 64, 732–737 (2015). https://doi.org/10.1007/s11172-015-0927-1

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  • DOI: https://doi.org/10.1007/s11172-015-0927-1

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