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Synthesis of 9,9´,12,12´-substituted cobalt bis(dicarbollide) derivatives

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Abstract

A partial degradation of 9,12-disubstituted derivatives of ortho-carboranes 9,12-X2-1,2-C2B10H10 (X = Br, Alk, Ar) led to the corresponding substituted nido-carboranes [5,6-X2-7,8-C2B9H10]–, which on the reaction with cobalt(II) chloride gave new 9,9´,12,12´-tetrasubstituted derivatives of cobalt bis(dicarbollide) [9,9´,12,12´-X4-3,3´-Co(1,2-C2B9H9)2]–.

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References

  1. M. F. Hawthorne, T. D. Andrews, Chem. Commun., 1964, 443

    Google Scholar 

  2. M. F. Hawthorne, D. C. Young, T. D. Andrews, D. V. Hove, R. L. Pilling, A. D. Pitts, M. Reinjes, L. F. Warren, P. A. Wegner, J. Am. Chem. Soc., 1968, 90, 879.

    Article  CAS  Google Scholar 

  3. I. B. Sivaev, V. I. Bregadze, Collect. Czech. Chem. Commun., 1999, 64, 783.

    Article  CAS  Google Scholar 

  4. I. B. Sivaev, V. I. Bregadze, Polyhedral Boron Hybrides in Use: Current Status and Perspectives, Nova Science Publishers, New York, 2009.

    Google Scholar 

  5. R. N. Grimes, Carboranes, Academic Press, London, 2011.

    Google Scholar 

  6. J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, M. H. Whangbo, Organic Superconductors (Including Fullerenes: Synthesis, Structure, Properties, and Theory), Prentice Hall, Englewood Cliffs, 1992.

    Google Scholar 

  7. R. P. Shibaeva, S. S. Khasanov, L. V. Zorina, S. V. Simonov, Crystallogr. Rep. (Engl. Transl.), 2006, 51, 949 [Kristallogr., 2006, 51, 1014].

    Article  CAS  Google Scholar 

  8. O. N. Kazheva, A. V. Kravchenko, G. G. Alexandrov, I. B. Sivaev, V. I. Bregadze, I. D. Kosenko, I. A. Lobanova, L. I. Buravov, V. A. Starodub, O. Dyachenko, Russ. Chem. Bull. (Int. Ed.), 2014, 63, 1322 [Izv. Akad. Nauk, Ser. Khim., 2014, 1322].

    Article  CAS  Google Scholar 

  9. O. Kazheva, G. Alexandrov, A. Kravchenko, V. Starodub, I. Lobanova, I. Sivaev, V. Bregadze, L. Buravov, O. Dyachenko, Solid State Sci., 2008, 10, 1734.

    Article  CAS  Google Scholar 

  10. O. N. Kazheva, G. G. Alexandrov, A. V. Kravchenko, V. A. Starodub, I. A. Lobanova, I. B. Sivaev, V. I. Bregadze, L. V. Titov, L. I. Buravov, O. A. Dyachenko, J. Organomet. Chem., 2009, 694, 2336.

    Article  CAS  Google Scholar 

  11. O. N. Kazheva, G. G. Alexandrov, A. V. Kravchenko, V. A. Starodub, I. B. Sivaev, I. A. Lobanova, V. I. Bregadze, L. I. Buravov, O. A. Dyachenko, J. Organomet. Chem., 2007, 692, 5033.

    Article  CAS  Google Scholar 

  12. O. N. Kazheva, G. G. Alexandrov, A. V. Kravchenko, I. D. Kosenko, I. A. Lobanova, I. B. Sivaev, O. A. Filippov, E. S. Shubin, V. I. Bregadze, V. A. Starodub, L. V. Titov, L. I. Buravov, O. A. Dyachenko, Inorg. Chem., 2011, 50, 444.

    Article  CAS  Google Scholar 

  13. O. N. Kazheva, G. G. Aleksandrov, A. V. Kravchenko, V. A. Starodub, G. G. Zhigareva, I. B. Sivaev, V. I. Bregadze, L. I. Buravov, L. V. Titov, O. A. D´yachenko, Russ. Chem. Bull. (Int. Ed.), 2010, 59, 1137 [Izv. Akad. Nauk, Ser. Khim., 2010, 1115].

    Article  CAS  Google Scholar 

  14. V. I. Bregadze, S. V. Timofeev, I. B. Sivaev, I. A. Lobanova, Russ. Chem. Rev., 2004, 73, 433.

    Article  CAS  Google Scholar 

  15. L. Matel, F. Macašek, P. Rajec, S, Hemanek, J. Plešek, Polyhedron, 1982, 1, 511.

    Article  CAS  Google Scholar 

  16. H. D. Smith, T. A. Knowles, H. Schroeder, Inorg. Chem., 1965, 4, 107.

    Article  CAS  Google Scholar 

  17. Z. Zheng, W. Jiang, A. A. Zinn, C. B. Knobler, M. F. Hawthorne, Inorg. Chem., 1995, 34, 2095.

    Article  CAS  Google Scholar 

  18. M. J. Bayer, A. Herzog, M. Diaz, G. A. Harakas, H. Lee, C. B. Knobler, M. F. Hawthorne, Chem. Eur. J., 2003, 9, 2732.

    Article  CAS  Google Scholar 

  19. M. A. Fox, K. Wade, J. Mater. Chem., 2002, 12, 1301.

    Article  CAS  Google Scholar 

  20. H. Lee, C. B. Knobler, M. F. Hawthorne, Chem. Commun., 2000, 2485.

    Google Scholar 

  21. G. Laurent, S.-J. Laurent, Tetrahedron Lett., 2006, 47, 5705.

    Article  Google Scholar 

  22. G. Brauer, Handbuch der Präparativen Anorganischen Chemie, Bd. 3, Stuttgart, Ferdinnd Enke Verlag, 1981.

    Google Scholar 

  23. A. R. Siedle, G. M. Bodner, L. J. Todd, J. Organomet. Chem., 1971, 33, 137.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. A. Anufriev, I. B. Sivaev & V. I. Bregadze

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  1. S. A. Anufriev
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  2. I. B. Sivaev
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  3. V. I. Bregadze
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Correspondence to I. B. Sivaev.

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Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0712—0717, March, 2015.

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Anufriev, S.A., Sivaev, I.B. & Bregadze, V.I. Synthesis of 9,9´,12,12´-substituted cobalt bis(dicarbollide) derivatives. Russ Chem Bull 64, 712–717 (2015). https://doi.org/10.1007/s11172-015-0924-4

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  • DOI: https://doi.org/10.1007/s11172-015-0924-4

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