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36-Nuclear CoII and NiII dimethylmalonate complexes with the [K(18-crown-6)]+ cationic fragments: synthesis and structure

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Abstract

A reaction of potassium dimethylmalonate (K2Me2Mal) with cobalt(II) or nickel(II) trimethylacetate in the presence of 18-crown-6 leads to the formation of 36-nuclear complexes {[K(18-crown-6)]2[K(H2O)(18-crown-6)]2[K6Co36(H2O)20(OH)18(Me2Mal)30(18-crown6)2(O)2]•xH2O} n (2) and {[K(H2O)2(18-crown-6)]6[K5Ni36(H2O)20(OH)18(18-crown-6)2(Me2Mal)28(HMe2Mal)2]4[K5Ni36(H2O)20(OH)20(18-crown-6)2(Me2Mal)29(HMe2Mal)]• •80H2O} n (3) (Me2Mal2– is the dianion of dimethylmalonic acid), respectively. The single crystal X-ray diffraction studies showed that the spherical 36-nuclear polyanions [Co36(H2O)12(OH)18(Me2Mal)30(O)2]10– (in compound 2) and [Ni36(H2O)12(OH)20(Me2Mal)30–x (HMe2Mal) x ]y– (in compound 3; x = 1, y = 7; x = 2, y = 6) have similar structures, with their metal cores being formed of two layers: an internal one comprising 24 metal atoms and an external containing 12 metal centers. The inner cavity of the {MII 36} anions was found to include one K+ aqua cation bonded to the oxygen atoms of the carboxylate or oxo ligands.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    E. N. Zorina-Tikhonova, N. V. Gogoleva, A. A. Sidorov, M. A. Kiskin & I. L. Eremenko

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  1. E. N. Zorina-Tikhonova
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  2. N. V. Gogoleva
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  3. A. A. Sidorov
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  4. M. A. Kiskin
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  5. I. L. Eremenko
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Correspondence to E. N. Zorina-Tikhonova.

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Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0636—0641, March, 2015.

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Zorina-Tikhonova, E.N., Gogoleva, N.V., Sidorov, A.A. et al. 36-Nuclear CoII and NiII dimethylmalonate complexes with the [K(18-crown-6)]+ cationic fragments: synthesis and structure. Russ Chem Bull 64, 636–641 (2015). https://doi.org/10.1007/s11172-015-0911-9

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  • DOI: https://doi.org/10.1007/s11172-015-0911-9

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