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Synthesis, rheological, and thermal properties of polydimethylsiloxanes modified with long-chain hydrocarbon substituents with polar fragments

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Abstract

A number of polydimethylsiloxanes modified with long-chain hydrocarbon substituents with ester or benzylamide terminal groups was synthesized by hydrosilylation and polymeranalogous reactions. The copolymers were characterized by 1H NMR spectroscopy, gel permeation chromatography, and differential scanning calorimetry. The influence of the type and content of modifying substituents on the low-temperature and rheological properties of the copolymers was established and indicates an increased level of intermolecular interactions in the synthesized copolymers compared to PDMS.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    T. A. Pryakhina, D. I. Shragin, Yu. N. Kononevich, V. G. Vasil´ev, M. I. Buzin, V. S. Papkov & A. M. Muzafarov

  2. N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    D. I. Shragin & A. M. Muzafarov

  3. V. I. Lenin Moscow Pedagogical State University, Building 1, 1 ul. Malaya Pirogovskaya, 119992, Moscow, Russian Federation

    M. I. Buzin

Authors
  1. T. A. Pryakhina
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  2. D. I. Shragin
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  3. Yu. N. Kononevich
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  4. V. G. Vasil´ev
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  5. M. I. Buzin
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  6. V. S. Papkov
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  7. A. M. Muzafarov
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Corresponding author

Correspondence to T. A. Pryakhina.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0605—0612, March, 2015.

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Pryakhina, T.A., Shragin, D.I., Kononevich, Y.N. et al. Synthesis, rheological, and thermal properties of polydimethylsiloxanes modified with long-chain hydrocarbon substituents with polar fragments. Russ Chem Bull 64, 605–612 (2015). https://doi.org/10.1007/s11172-015-0906-6

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  • DOI: https://doi.org/10.1007/s11172-015-0906-6

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