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Properties of polyelectrolytes prepared by polymerization of ionogenic monomers in micellar solutions of sodium dodecyl sulfate

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Abstract

The properties of polyelectrolytes obtained by the free radical and template polymerization of N-ethyl-N,N-dimethyl-N-methacryloyloxyethylammonium bromide, trimethylmethacryloyloxyethylammonium methyl sulfate, and [N-benzyl-N,N-dimethyl-N-(methacryloyloxyethyl)]ammonium chloride in micellar solutions of sodium dodecyl sulfate were studied by static and dynamic light scattering, viscosimetry, and differential refractometer. It was shown that the solubility of the polymerization products, being polyelectrolyte—surfactant complexes, is determined by the composition of the reaction mixture and chemical nature of the monomer. The introduction of a surfactant into the polymerization medium noticeably decreases the molecular weight of the formed polymers.

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Authors and Affiliations

  1. Volgograd State Technical University, 28 prosp. Lenina, 400005, Volgograd, Russian Federation

    I. A. Novakov, Yu. V. Shulevich, Le Tkhi Doan Chang, E. G. Dukhanina & A. V. Navrotskii

  2. Chemical Department, M. V. Lomonosov Moscow State University, 1/3 Leninskie Gory, 119992, Moscow, Russian Federation

    Yu. A. Zakharova

Authors
  1. I. A. Novakov
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  2. Yu. V. Shulevich
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  3. Yu. A. Zakharova
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  4. Le Tkhi Doan Chang
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  5. E. G. Dukhanina
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  6. A. V. Navrotskii
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Corresponding author

Correspondence to Yu. V. Shulevich.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0597—0604, March, 2015.

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Novakov, I.A., Shulevich, Y.V., Zakharova, Y.A. et al. Properties of polyelectrolytes prepared by polymerization of ionogenic monomers in micellar solutions of sodium dodecyl sulfate. Russ Chem Bull 64, 597–604 (2015). https://doi.org/10.1007/s11172-015-0905-7

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  • DOI: https://doi.org/10.1007/s11172-015-0905-7

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