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Alkylation of NH-, OH-, and SH-acids in the presence of potassium carbonate

1. Functionalization of chloromethyl group of alkoxy-substituted aromatic aldehydes

Russian Chemical Bulletin volume 64, pages 395–404 (2015)Cite this article

Abstract

An easily scalable, economocal, and more safe method for the preparation of 3-chloromethyl-4-methoxybenzaldehyde was developed. The latter was subjected to reactions with NH-, OH-, and SH-acids in the presence of potassium carbonate to obtain new aromatic aldehydes in high yields.

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Authors and Affiliations

  1. Labor Red Banner order Federal State Unitary Enterprise “Research Institute of Chemical Reactants and Ultrapure Compounds (IREA)”, 3 Bogorodskii val, 107076, Moscow, Russian Federation

    D. S. Khachatryan, A. L. Razinov, A. V. Kolotaev & S. K. Belus´

  2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    K. R. Matevosyan

Authors
  1. D. S. Khachatryan
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  2. A. L. Razinov
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  3. A. V. Kolotaev
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  4. S. K. Belus´
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  5. K. R. Matevosyan
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Correspondence to D. S. Khachatryan.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0395—0404, February, 2015.

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Khachatryan, D.S., Razinov, A.L., Kolotaev, A.V. et al. Alkylation of NH-, OH-, and SH-acids in the presence of potassium carbonate. Russ Chem Bull 64, 395–404 (2015). https://doi.org/10.1007/s11172-015-0875-9

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  • DOI: https://doi.org/10.1007/s11172-015-0875-9

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