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Amine acceleration of oxidation of styrene epoxide with oxygen in acidic media

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Abstract

Additives of aromatic amines (aniline, α-naphtylamine, o-, p-, and m-aminophenols) accelerate the low-temperature (343 K) molecular oxygen uptake by styrene epoxides in acetonitrile solution of toluenesulfonic acid. Amines decrease the output of benzaldehyde (oxidation product) and nearly suppress the formation of phenylacetaldehyde, the product of acid-catalyzed conversion of styrene epoxide.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    L. V. Petrov & V. M. Solyanikov

Authors
  1. L. V. Petrov
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  2. V. M. Solyanikov
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Correspondence to L. V. Petrov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0107–0111, January, 2015.

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Petrov, L.V., Solyanikov, V.M. Amine acceleration of oxidation of styrene epoxide with oxygen in acidic media. Russ Chem Bull 64, 107–111 (2015). https://doi.org/10.1007/s11172-015-0828-3

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  • DOI: https://doi.org/10.1007/s11172-015-0828-3

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