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Synthesis of new acids based on bis(dicarbollide)cobalt

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Abstract

New acids based on bis(dicarbollide)cobalt [8-HOOC(CH2) n NH2(CH2CH2O)2-3,3’-Co(1,2-C2B9H10)(1’,2’-C2B9H11)] (n = 1, 3) were obtained by the reaction of its 1,4-dioxane derivative with ω-amino acid esters and subsequent removal of the protection.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. V. Shmal’ko, I. B. Sivaev & V. I. Bregadze

  2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    A. V. Shmal’ko & L. V. Kovalenko

Authors
  1. A. V. Shmal’ko
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  2. I. B. Sivaev
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  3. V. I. Bregadze
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  4. L. V. Kovalenko
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Corresponding author

Correspondence to I. B. Sivaev.

Additional information

Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80th birthday and to the 60th anniversary of the foundation of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2334–2337, October, 2014.

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Shmal’ko, A.V., Sivaev, I.B., Bregadze, V.I. et al. Synthesis of new acids based on bis(dicarbollide)cobalt. Russ Chem Bull 63, 2334–2337 (2014). https://doi.org/10.1007/s11172-014-0743-z

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  • DOI: https://doi.org/10.1007/s11172-014-0743-z

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