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Palladium(II) aminoiminophosphoranate complexes as cross-coupling catalysts

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Abstract

The Tsuji-Trost reaction between diethyl malonate and allyl acetate catalyzed by palladium(II) NPN-aminoiminophosphoranate complexes yields mono- and diallylation products in the ratios depending on the complex used. The Suzuki-Miyaura cross-coupling of 4-bromoacetophenone with phenylboronic acid catalyzed by these palladium complexes proceeds with 66–99.5% conversions.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    T. A. Peganova, A. M. Kalsin & N. A. Ustynyuk

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Vasil’ev

Authors
  1. T. A. Peganova
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  2. A. M. Kalsin
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  3. N. A. Ustynyuk
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  4. A. A. Vasil’ev
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Corresponding authors

Correspondence to A. M. Kalsin or A. A. Vasil’ev.

Additional information

Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80th birthday and the 60th anniversary of the foundation of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2305–2308, October, 2014.

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Peganova, T.A., Kalsin, A.M., Ustynyuk, N.A. et al. Palladium(II) aminoiminophosphoranate complexes as cross-coupling catalysts. Russ Chem Bull 63, 2305–2308 (2014). https://doi.org/10.1007/s11172-014-0739-8

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  • DOI: https://doi.org/10.1007/s11172-014-0739-8

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