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Synthesis of hydroxyethyl starch derivatives with phenylpropanoid fragments attached through ester or sulfide bonds

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Abstract

Approaches to the synthesis of hydroxyethyl starch derivatives containing phenylpropanoic acid fragments with various degree of substitution were suggested. Esterification of hydroxyethyl starch in heterogeneous aqueous organic medium gave rise to the corresponding esters of ferulic, p-coumaric, and sinapinic acids. A reaction of hydroxyethyl starch mercaptodeoxy derivative with acetoxy derivatives of these hydroxycinnamic acids led to the mixed polysaccharides with the oxyphenyl-3-mercaptopropanoic acid fragments.

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Correspondence to E. V. Udoratina.

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Based on the materials of the VIII All-Russian Conference "Chemistry and Technology of Plant Substances" (October 7–10, 2013, Kaliningrad).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2130–2135, September, 2014.

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Torlopov, M.A., Udoratina, E.V. & Belyaev, V.Y. Synthesis of hydroxyethyl starch derivatives with phenylpropanoid fragments attached through ester or sulfide bonds. Russ Chem Bull 63, 2130–2135 (2014). https://doi.org/10.1007/s11172-014-0710-8

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  • DOI: https://doi.org/10.1007/s11172-014-0710-8

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