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Study of ferrocene derivatives Fe(C5H4X)(C5H5−n Y n ) by cyclic voltammetry and matrix-activated laser desorption/ionization time-of-flight mass spectrometry

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Abstract

A complex approach based on the combined use of MALDI time-of-flight mass spectrometry and cyclic voltammetry was applied for the first time to study the redox properties of ferrocene derivatives Fe(C5H4X)(C5H5−n Y n ). A comparison of the oxidation (reduction) potentials of the analyzed substance and matrix makes it possible to choose the type of the matrix and the needed operating mode of the instrument. Mass spectra detected in the positive ion mode are most informative for the ferrocene derivatives.

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Authors and Affiliations

  1. Lobachevsky State University of Nizhni Novgorod, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    I. D. Grishin & K. S. Agafonova

Authors
  1. I. D. Grishin
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  2. K. S. Agafonova
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Correspondence to I. D. Grishin.

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According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamental and Applied Aspects” (September 1–7, 2013, Nizhnii Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0976–0982, April, 2014.

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Grishin, I.D., Agafonova, K.S. Study of ferrocene derivatives Fe(C5H4X)(C5H5−n Y n ) by cyclic voltammetry and matrix-activated laser desorption/ionization time-of-flight mass spectrometry. Russ Chem Bull 63, 976–982 (2014). https://doi.org/10.1007/s11172-014-0536-4

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  • DOI: https://doi.org/10.1007/s11172-014-0536-4

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