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Reactivity of Cp*M (M = Co, Rh, Ir) half-sandwich complexes containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligand with organic azides

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Abstract

The reactivity of unsaturated 16-electron half-sandwich complexes Cp*M(S2C2B10H10) (Cp* is pentamethylcyclopentadienyl, M = Co, Rh, Ir) towards various organic azides was studied. The difference in the metal center and organic azides led to products with different coordination modes, which were characterized by 1H, 11B, and 13C NMR spectroscopy, IR spectroscopy, elemental analysis, and X-ray diffraction.

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Authors and Affiliations

  1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu, 210093, China

    W. Zhong, H. Yan & Y. Li

  2. College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang, 314001, China

    W. Zhong

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. I. Bregadze

Authors
  1. W. Zhong
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  2. H. Yan
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  3. Y. Li
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  4. V. I. Bregadze
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Corresponding author

Correspondence to H. Yan.

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According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamentals and Applied Aspects” (September 1–7, 2013, Nizhniy Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0953–0962, April, 2014.

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Zhong, W., Yan, H., Li, Y. et al. Reactivity of Cp*M (M = Co, Rh, Ir) half-sandwich complexes containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligand with organic azides. Russ Chem Bull 63, 953–962 (2014). https://doi.org/10.1007/s11172-014-0533-7

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  • DOI: https://doi.org/10.1007/s11172-014-0533-7

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