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Binuclear terbium(iii) pivalates with 4,7-diphenyl-1,10-phenanthroline: synthesis, structure, thermal decomposition, and magnetic and luminescence properties

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Abstract

New binuclear pivalate complexes (bath)2Tb2(piv)6 and (bath)2Tb2(piv)6·H2O (piv = = ButCCO2 −, bath is 4,7-diphenyl-1,10-phenanthroline) were synthesized. The thermal behavior of these complexes was studied by differential scanning calorimetry and thermogravimetric analysis. The composition of the complexes in the gas phase was determined, and their magnetic and photoluminescence properties were studied. The structures of the compounds (bath)2Tb2(piv)6 and (bath)2Tb2(piv)6·H2O were determined by X-ray diffraction.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    I. G. Fomina, Zh. V. Dobrokhotova, A. B. Ilyukhin, G. G. Aleksandrov, A. V. Gavrikov, A. E. Gekhman, V. M. Novotortsev & I. L. Eremenko

  2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    A. S. Bogomyakov

  3. D. V. Skobeltsyn Institute of Nuclear Physics, M. V. Lomonosov Moscow State University, Build. 2, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    Yu. S. Zavorotnyi & V. I. Gerasimova

Authors
  1. I. G. Fomina
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  2. Zh. V. Dobrokhotova
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  3. A. B. Ilyukhin
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  4. G. G. Aleksandrov
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  5. A. V. Gavrikov
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  6. A. S. Bogomyakov
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  7. A. E. Gekhman
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  8. Yu. S. Zavorotnyi
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  9. V. I. Gerasimova
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  10. V. M. Novotortsev
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  11. I. L. Eremenko
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Corresponding author

Correspondence to I. G. Fomina.

Additional information

According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamental and Applied Aspects” (September 1–7, 2013, Nizhny Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0938–0944, April, 2014.

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Fomina, I.G., Dobrokhotova, Z.V., Ilyukhin, A.B. et al. Binuclear terbium(iii) pivalates with 4,7-diphenyl-1,10-phenanthroline: synthesis, structure, thermal decomposition, and magnetic and luminescence properties. Russ Chem Bull 63, 938–944 (2014). https://doi.org/10.1007/s11172-014-0531-9

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  • DOI: https://doi.org/10.1007/s11172-014-0531-9

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