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Complex of triphenylantimony(v) catecholate with 5-(2,6-dimethylphenyl)-3-(4-pyridyl)-1-phenylformazan

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Abstract

The complex of triphenylantimony(V) 3,6-di-tert-butylcatecholate with 5-(2,6-dimethylphenyl)-3-(4-pyridyl)-1-phenylformazan was synthesized and characterized by spectroscopic and electrochemical methods and by X-ray diffraction. In the crystal structure, there are intermolecular hydrogen bonds between the formazan ligands of adjacent molecules. The electrochemical transformations of the complex were investigated by cyclic voltammetry. It was shown that both the formazan and catecholate moieties are involved in redox processes.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    N. A. Protasenko, A. I. Poddel’skii, G. K. Fukin, V. K. Cherkasov & G. A. Abakumov

  2. N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    A. I. Poddel’skii & V. K. Cherkasov

  3. Research Group of Toxicology, Southern Scientific Center, Russian Academy of Sciences, 16 ul. Tatishcheva, 414025, Astrakhan, Russian Federation

    I. V. Smolyaninov & N. T. Berberova

Authors
  1. N. A. Protasenko
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  2. A. I. Poddel’skii
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  3. I. V. Smolyaninov
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  4. N. T. Berberova
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  5. G. K. Fukin
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  6. V. K. Cherkasov
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  7. G. A. Abakumov
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Corresponding author

Correspondence to A. I. Poddel’skii.

Additional information

According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamental and Applied Aspects“ (September 1–7, 2013, Nizhny Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0930–0937, April, 2014.

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Protasenko, N.A., Poddel’skii, A.I., Smolyaninov, I.V. et al. Complex of triphenylantimony(v) catecholate with 5-(2,6-dimethylphenyl)-3-(4-pyridyl)-1-phenylformazan. Russ Chem Bull 63, 930–937 (2014). https://doi.org/10.1007/s11172-014-0530-x

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  • DOI: https://doi.org/10.1007/s11172-014-0530-x

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