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Novel 1,10-diaza-18-crown-6 derivatives

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Abstract

Reaction of 1,10-bis(methoxymethyl)-1,10-diaza-18-crown-6 (1) with trimethylsilyl azide resulted in hitherto unknown 1,10-bis(azidomethyl)-1,10-diaza-18-crown-6 (2) and novel ionic compound 1,10-bis(azide anion)-1,10-dihydro-1,10-diaza-18-crown-6 (3). Compound 2 rnneacted with dimethyl acetylenedicarboxylate to give 1,10-bis(4,5-dimethoxycarbonyltriazolomethyl)-1,10-diaza-18-crown-6 (4). Carbamoylation of 1,10-diaza-18-crown-6 (5) with optically active α-phenylethyl amine yielded optically active 1,10-bis(α-phenylethylcarbamoyl)-1,10-diaza-18-crown-6 (6).

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References

  1. O. G. Nabiev, Z. O. Nabizade, R. G. Kostyanovsky, Mendeleev Commun., 2009, 19, 281.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    R. G. Kostyanovsky, O. G. Nabiev, G. K. Kadorkina & I. I. Chervin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. A. Lyssenko

Authors
  1. R. G. Kostyanovsky
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  2. K. A. Lyssenko
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  3. O. G. Nabiev
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  4. G. K. Kadorkina
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  5. I. I. Chervin
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Corresponding author

Correspondence to R. G. Kostyanovsky.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0772–0774, March, 2014.

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Kostyanovsky, R.G., Lyssenko, K.A., Nabiev, O.G. et al. Novel 1,10-diaza-18-crown-6 derivatives. Russ Chem Bull 63, 772–774 (2014). https://doi.org/10.1007/s11172-014-0507-9

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  • DOI: https://doi.org/10.1007/s11172-014-0507-9

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