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Asymmetric hydrogenation of diethyl 1-phenylvinylphosphonate by metal complexes in CH2Cl2 and in supercritical carbon dioxide using phosphite-type ligands

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Abstract

Asymmetric hydrogenation of diethyl 1-phenylvinylphosphonate was carried out for the first time in dichloromethane and supercritical carbon dioxide in the presence of phosphite and amidophosphite ligands. The catalysts based on [Ir(COD)2]BARF (COD is 1,5-cyclooctadiene, BARF is tetrakis[3,5-bis(trifluoromethyl)phenyl]borate anion), provide higher enantioselectivity than [Ir(COD)Cl]2 and [Rh(COD)2]BF4 do.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. V. Ozolin, S. E. Lyubimov & V. A. Davankov

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  1. D. V. Ozolin
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  2. S. E. Lyubimov
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  3. V. A. Davankov
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Correspondence to S. E. Lyubimov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0693–0695, March, 2014.

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Ozolin, D.V., Lyubimov, S.E. & Davankov, V.A. Asymmetric hydrogenation of diethyl 1-phenylvinylphosphonate by metal complexes in CH2Cl2 and in supercritical carbon dioxide using phosphite-type ligands. Russ Chem Bull 63, 693–695 (2014). https://doi.org/10.1007/s11172-014-0493-y

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  • DOI: https://doi.org/10.1007/s11172-014-0493-y

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