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Mechanochemical synthesis of triphenylmethylium and triphenylcyclopropenylium tetrakis(pentafluorophenyl)borates

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Abstract

A possibility of application of mechanochemical method for the synthesis of triphenylmethylium and triphenylcyclopropenylium tetrakis(pentafluorophenyl)borates by the solvent-free reaction of solid starting compounds was studied. Some specific features of these reactions were discovered. Preparative methods for the mechanochemical synthesis of these salts were developed. This method makes the process shorter and excludes the use of solvents in the synthesis.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. D. Makhaev, A. N. Galiullin, E. E. Faingol’d, N. M. Bravaya & L. A. Petrova

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  1. V. D. Makhaev
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  2. A. N. Galiullin
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  3. E. E. Faingol’d
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  4. N. M. Bravaya
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  5. L. A. Petrova
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Correspondence to V. D. Makhaev.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0651–0656, March, 2014.

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Makhaev, V.D., Galiullin, A.N., Faingol’d, E.E. et al. Mechanochemical synthesis of triphenylmethylium and triphenylcyclopropenylium tetrakis(pentafluorophenyl)borates. Russ Chem Bull 63, 651–656 (2014). https://doi.org/10.1007/s11172-014-0487-9

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  • DOI: https://doi.org/10.1007/s11172-014-0487-9

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