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Unusual reaction of 3-amino-1,2,4-triazole with 1,3-diiodopropan-2-one

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Abstract

3-Amino-1,4-bis(2-oxopropyl)-4H-1,2,4-triazolium triiodide is the product of the reaction of 3-amino-1,2,4-triazole with 1,3-diiodopropan-2-one in acetone in the absence of bases and phase-transfer catalysts. In dimethyl sulfoxide, conversely, a water soluble polyionene consisting of three aminotriazole rings bound by 1,3-dimethylenecarbonyl bridges is formed. The effect of the solvent on the alkylation of 3-amino-1,2,4-triazole with 1,3-diiodopropan-2-one was studied.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    M. G. Voronkov, L. G. Shagun, I. A. Dorofeev, L. V. Zhilitskaya, N. O. Yarosh & L. I. Larina

Authors
  1. M. G. Voronkov
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  2. L. G. Shagun
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  3. I. A. Dorofeev
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  4. L. V. Zhilitskaya
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  5. N. O. Yarosh
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  6. L. I. Larina
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Corresponding author

Correspondence to L. G. Shagun.

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Dedicated to Academician of the Russian Academy of Sciences M. P. Egorov on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2554—2556, Novemer, 2013.

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Voronkov, M.G., Shagun, L.G., Dorofeev, I.A. et al. Unusual reaction of 3-amino-1,2,4-triazole with 1,3-diiodopropan-2-one. Russ Chem Bull 62, 2554–2556 (2013). https://doi.org/10.1007/s11172-013-0371-z

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  • DOI: https://doi.org/10.1007/s11172-013-0371-z

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