Abstract
A one-pot method for the synthesis of polycyclic phospholanes and phospholane 3-oxides from norbornenes was developed based on their Cp2ZrCl2-catalyzed cycloalumination. The in situ formed polycyclic aluminacyclopentanes were treated with organic dichlorophosphines (RPCl2, where R = Me, But, Ph) to obtain polycyclic phospholanes. The phospholanes were oxidized with hydrogen peroxide to obtain their 3-oxides in 81–92% yields.
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Dedicated to Academician of the Russian Academy of Sciences M. P. Egorov on the occasion of his 60th birthday.
For Part 42, see Ref. 1.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2467–2471, Novemer, 2013.
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Makhamatkhanova, A.L., Dil’mukhametova, L.K., Tyumkina, T.V. et al. Synthesis and transformations of metallacycles 43. One-pot synthesis of polycyclic 3-alkyl(phenyl)phospholane 3-oxides. Russ Chem Bull 62, 2467–2471 (2013). https://doi.org/10.1007/s11172-013-0357-x
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DOI: https://doi.org/10.1007/s11172-013-0357-x