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Cycloaddition of electron-deficient olefins to norbornadiene in the presence of nickel bisphosphine systems

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Abstract

[2+2+2] Cycloaddition of electron-deficient olefins to norbornadiene in the presence of nickel bisphosphine catalysts was studied. The influence of the bisphosphine structure on the regio- and stereoselectivity of the reaction as well as on the yields of the reaction products was investigated. New evidence for the influence of chiral bisphosphine ligands on the enantioselectivity of the reaction was obtained.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University of Fine Chemical Technologies, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    D. V. Dmitriev, R. S. Shamsiev, Ha Ngok Thien & V. R. Flid

Authors
  1. D. V. Dmitriev
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  2. R. S. Shamsiev
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  3. Ha Ngok Thien
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  4. V. R. Flid
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Corresponding author

Correspondence to R. S. Shamsiev.

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Dedicated to Academician of the Russian Academy of Sciences M. P. Egorov on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2385–2388, Novemer, 2013.

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Dmitriev, D.V., Shamsiev, R.S., Thien, H.N. et al. Cycloaddition of electron-deficient olefins to norbornadiene in the presence of nickel bisphosphine systems. Russ Chem Bull 62, 2385–2388 (2013). https://doi.org/10.1007/s11172-013-0345-1

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  • DOI: https://doi.org/10.1007/s11172-013-0345-1

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