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Electrocatalytic fluoroalkylation of olefins. Nickel-catalyzed polyfluoroalkylation of allylisocyanurates

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Abstract

Electrochemical co-reduction of allylisocyanurates and polyfluoroalkyl halides in the presence of nickel complexes with α-diimine ligands results in the addition of the polyfluoroalkyl group to the C=C bond followed by dimerization of the intermediate adducts.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    Yu. B. Dudkina, D. Yu. Mikhailov, T. V. Gryaznova, S. G. Fattakhov, Yu. G. Budnikova & O. G. Sinyashin

Authors
  1. Yu. B. Dudkina
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  2. D. Yu. Mikhailov
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  3. T. V. Gryaznova
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  4. S. G. Fattakhov
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  5. Yu. G. Budnikova
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  6. O. G. Sinyashin
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Corresponding author

Correspondence to Yu. B. Dudkina.

Additional information

Dedicated to Academician of the Russian Academy of Sciences M. P. Egorov on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2362–2366, Novemer, 2013.

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Dudkina, Y.B., Mikhailov, D.Y., Gryaznova, T.V. et al. Electrocatalytic fluoroalkylation of olefins. Nickel-catalyzed polyfluoroalkylation of allylisocyanurates. Russ Chem Bull 62, 2362–2366 (2013). https://doi.org/10.1007/s11172-013-0342-4

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  • DOI: https://doi.org/10.1007/s11172-013-0342-4

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