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Detonation nanodiamonds as catalysts of steam reforming of ethanol

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Abstract

Physicochemical properties and catalytic performance of detonation nanodiamonds were studied. Original samples of nanodiamonds and nanodiamonds modified by hydrogen, oxygen, and nitric acid with hydrogen peroxide and infrared-treated were investigated. The catalyst structure and morphology were examined by transmission electron microscopy and IR spectroscopy. All the investigated catalysts were active in the steam reforming of ethanol. The correlation of catalytic properties with composition and structure of the described systems is discussed. The specific surface area of nanodiamonds is changed insignificantly upon modification.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prospect, 119991, Moscow, Russian Federation

    E. Yu. Mironova, M. M. Ermilova, M. N. Efimov, L. M. Zemtsov, N. V. Orekhova, G. P. Karpacheva, G. N. Bondarenko, N. A. Zhilyaeva & A. B. Yaroslavtsev

  2. Department of Chemistry, Autonomous University of BarceIona, E-08193, Bellaterra, Barcelona, Spain

    D. N. Muraviev

Authors
  1. E. Yu. Mironova
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  2. M. M. Ermilova
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  3. M. N. Efimov
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  4. L. M. Zemtsov
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  5. N. V. Orekhova
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  6. G. P. Karpacheva
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  7. G. N. Bondarenko
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  8. N. A. Zhilyaeva
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  9. D. N. Muraviev
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  10. A. B. Yaroslavtsev
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Corresponding author

Correspondence to A. B. Yaroslavtsev.

Additional information

Dedicated to Academician of the Russian Academy of Sciences M.P. Egorov on occasion of his 60th anniversary.

Analytical Chemistry Unit, Department of Chemistry, Autonomous University of Barcelona, 08193 Bellaterra, Barcelona, Spain.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2317–2321, Novemer, 2013.

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Mironova, E.Y., Ermilova, M.M., Efimov, M.N. et al. Detonation nanodiamonds as catalysts of steam reforming of ethanol. Russ Chem Bull 62, 2317–2321 (2013). https://doi.org/10.1007/s11172-013-0336-2

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  • DOI: https://doi.org/10.1007/s11172-013-0336-2

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