Abstract
Methods for the synthesis of 4-hydroxy-3-(polynitromethyl-ONN-azoxy)furazans, 4-alkoxy-3-(polynitromethyl-ONN-azoxy)furazans and their derivatives were developed, which included the substitution of the nitro group in 3-(dinitromethyl-ONN-azoxy)-4-nitrofurazan upon treatment with aqueous alkalis, mono- and diatomic alcohols (in the presence of inorganic bases) with subsequent nitration or fluorination of the nitroalkyl fragment in the substitution products formed.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2007–2011, September, 2013.
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Parakhin, V.V., Luk’yanov, O.A. 4-Hydroxy-3-(polynitromethyl-ONN-azoxy)furazans and some of their derivatives. Russ Chem Bull 62, 2007–2011 (2013). https://doi.org/10.1007/s11172-013-0291-y
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DOI: https://doi.org/10.1007/s11172-013-0291-y
Key words
- furazans
- (a-polynitroalkyl-ONN-azoxy)furazans
- 4-hydroxy-3-(polynitromethyl-ONN-azoxy)furazans
- 4-hydroxy-3-(trinitromethyl-ONN-azoxy)furazans
- 4-hydroxy-3-(halodinitromethyl-ONN-azoxy)furazans
- 3,3′-bis(polynitromethyl-ONN-azoxy)-4,4′-difurazanyl ethers
- nitrofurazans
- hydroxyfurazans
- nucleophilic substitution
- nitration
- halogenation