Skip to main content
SpringerLink
Log in

Synthesis, structure, and properties of polynuclear molybdenum(v,vi) oxomethoxides with magnesium

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

General conditions for the formation of heterometallic clusters by the simultaneous methanolysis of MoCl5 and MgCl2 were determined. The resultant alkalinity of the reaction solution, the Mg/Mo molar ratio, and the presence of traces of water are key factors responsible for the composition and structure of the mixed magnesium molybdenum methoxides that formed. The new decanuclear mixed-valence MoV,VI Mg oxomethoxide [MoV 4O4(μ3-O)2(μ2-O)2MoVI 2-O4(OMe)2Mg4(MeOH)6(μ3-OMe)6(μ2-OMe)8] (1) was synthesized by the reaction of lowernuclearity magnesium molybdenum oxoalkoxide complexes: NaMoV of the complex Na(MeOH)MoV 2O2(μ2-OMe)3(OMe)4 (2) and MgMoVI of the complex [MoVIO2Mg(MeOH)2-(OMe)4]2 (3). The molecular structure of 1 was determined by X-ray diffraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. A. Bazhenova, A. E. Shilov, Coord. Chem. Rev., 1995, 114, 69.

    Article  Google Scholar 

  2. L. P. Didenko, A. E. Shilov, A. K. Shilova, Kinet. Katal., 1979, 1488 [Kinet. Catal. (Engl. Transl.), 1979, 20].

    Google Scholar 

  3. A. E. Shilov, in Electron Transfer in Chemistry, Ed. V. Balzani, Wiley-VCH, Weinheim, 2001, 899.

  4. N. T. Denisov, N. I. Shuvalova, React. Kinet. Catal. Lett., 1976, 4, 431

    Article  CAS  Google Scholar 

  5. N. T. Denisov, A. I. Korosteleva, Yu. I. Morozov, S. I. Kobeleva, Kinet. Katal., 1977, 758 [Kinet. Catal. (Engl. Transl.), 1977, 18].

    Google Scholar 

  6. T. A. Bazhenova, K. A. Lyssenko, D. A. Kuznetsov, N. V. Kovaleva, Y. V. Manakin, T. A. Savinykh, A. F. Shestakov, J. Chem. Soc., Dalton Trans., 2013, submitted.

    Google Scholar 

  7. G. M. Sheldrick, Acta Crystallogr., Sect. A, 2007, 64, 112.

    Article  Google Scholar 

  8. F. H. Allen, Acta Crystallogr., Sect. B, 2002, 58, 380.

    Article  Google Scholar 

  9. N. V. Bardina, T. A. Bazhenova, K. A. Lissenko, M. Yu. Antipin, Yu. M. Shulga, T. A. Filina, A. F. Shestakov, Mendeleev Commun., 2006, 16, 307.

    Article  Google Scholar 

  10. C. Limberg, A. J. Downs, A. J. Blake, S. Parsons, Inorg. Chem., 1996, 35, 4439.

    Article  CAS  Google Scholar 

  11. K. J. Moynihan, P. M. Boorman, J. M. Ball, V. D. Patel, K. A. Kerr, Acta Crystallogr., Sect. B, 1982, 38, 2258.

    Article  Google Scholar 

  12. M. Yu. Antipin, Yu. T. Struchkov, A. E. Shilov, A. K. Shilova, Gazz. Chim. Ital., 1993, 123, 265.

    CAS  Google Scholar 

  13. V. G. Kessler, Chem. Commun., 2003, 1213.

    Google Scholar 

  14. J. A. Ibers, Nature, 1963, 197, 686.

    Article  CAS  Google Scholar 

  15. S. A. Al’tshuler, B. M. Kozyrev, EPR soedinenii elementov promezhutochnykh grupp [ESR of Compounds of Intermediate-Group Elements], Nauka, Moscow, 1972, 672 pp (in Russian).

    Google Scholar 

  16. D. L. Kepert, Inorg. Chem., 1969, 8, 1556.

    Article  CAS  Google Scholar 

  17. B. Modec, Yu. V. Brencic, J. Zubieta, J. Chem. Soc., Dalton Trans., 2002, 1500.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    Yu. V. Manakin, D. A. Kuznetsov, N. V. Kovaleva, A. V. Kulikov & T. A. Bazhenova

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. V. Fedyanin & K. A. Lyssenko

Authors
  1. Yu. V. Manakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Fedyanin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. A. Lyssenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. V. Kovaleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. V. Kulikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. T. A. Bazhenova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to K. A. Lyssenko or T. A. Bazhenova.

Additional information

Dedicated to the memory of the Corresponding Member of the Russian Academy of Sciences M. Yu. Antipin (1951–2013).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1843–1851, August, 2013.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Manakin, Y.V., Kuznetsov, D.A., Fedyanin, I.V. et al. Synthesis, structure, and properties of polynuclear molybdenum(v,vi) oxomethoxides with magnesium. Russ Chem Bull 62, 1843–1851 (2013). https://doi.org/10.1007/s11172-013-0265-0

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-013-0265-0

Key words

Search

Navigation