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Synthesis of diethoxy(phenyl)silane and its polycondensation in acetic acid

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Abstract

Low-temperature reaction between phenylmagnesium chloride and triethoxysilane at lowered affords diethoxy(phenyl)silane, whose polycondensation in acetic acid gives oligomeric (phenyl)hydrosiloxanes.

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Authors and Affiliations

  1. N. S. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    S. A. Milenin, A. A. Kalinina, N. V. Demchenko, N. G. Vasilenko & A. M. Muzafarov

Authors
  1. S. A. Milenin
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  2. A. A. Kalinina
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  3. N. V. Demchenko
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  4. N. G. Vasilenko
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  5. A. M. Muzafarov
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Corresponding author

Correspondence to S. A. Milenin.

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Dedicated to the Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0705–0709, March, 2013.

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Milenin, S.A., Kalinina, A.A., Demchenko, N.V. et al. Synthesis of diethoxy(phenyl)silane and its polycondensation in acetic acid. Russ Chem Bull 62, 705–709 (2013). https://doi.org/10.1007/s11172-013-0096-z

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  • DOI: https://doi.org/10.1007/s11172-013-0096-z

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