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Carboxylated and decarboxylated nanotubes studied by X-ray photoelectron spectroscopy

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Abstract

Carbon nanotubes (CNTs) of the conic and cylindrical structure were studied by X-ray photoelectron spectroscopy in the initial state and after carboxylation and decarboxylation reactions. The O=C—O and C—O groups were revealed on the surface of the chemically modified samples. It was found that both the carboxylated and decarboxylated cylindrical CNTs contain a smaller amount of oxygen than the corresponding conic CNTs apparently due to differences in their structures.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    T. M. Ivanova, S. V. Savilov & V. V. Lunin

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Building 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    K. I. Maslakov, S. V. Savilov, A. S. Ivanov, A. V. Egorov & V. V. Lunin

  3. Russian University of Peoples’ Friendship, 6 ul. Miklukho-Maklaya, 117198, Moscow, Russian Federation

    R. V. Linko

Authors
  1. T. M. Ivanova
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  2. K. I. Maslakov
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  3. S. V. Savilov
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  4. A. S. Ivanov
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  5. A. V. Egorov
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  6. R. V. Linko
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  7. V. V. Lunin
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Corresponding author

Correspondence to K. I. Maslakov.

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Dedicated to the Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0639–0644, March, 2013.

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Ivanova, T.M., Maslakov, K.I., Savilov, S.V. et al. Carboxylated and decarboxylated nanotubes studied by X-ray photoelectron spectroscopy. Russ Chem Bull 62, 640–645 (2013). https://doi.org/10.1007/s11172-013-0086-1

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  • DOI: https://doi.org/10.1007/s11172-013-0086-1

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