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CuCl-Catalyzed ring-opening isomerization of gem-chlorofluorocyclopropanes with the formation of chlorofluoroalkenes and chlorofluoroalkadienes

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Abstract

The ability of copper(I) chloride to catalyze the ring-opening isomerization of alkyl-, phenyl-, vinyl-, and cyclopropyl-substituted gem-chlorofluorocyclopropanes to chlorofluoroalkenes or chlorofluoroalkadienes was found.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    M. A. Novikov, N. V. Volchkov, M. B. Lipkind & O. M. Nefedov

Authors
  1. M. A. Novikov
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  2. N. V. Volchkov
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  3. M. B. Lipkind
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  4. O. M. Nefedov
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Corresponding author

Correspondence to N. V. Volchkov.

Additional information

For preliminary communication, see Ref. 11.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0071–0082, January, 2013.

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Novikov, M.A., Volchkov, N.V., Lipkind, M.B. et al. CuCl-Catalyzed ring-opening isomerization of gem-chlorofluorocyclopropanes with the formation of chlorofluoroalkenes and chlorofluoroalkadienes. Russ Chem Bull 62, 71–82 (2013). https://doi.org/10.1007/s11172-013-0009-1

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  • DOI: https://doi.org/10.1007/s11172-013-0009-1

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