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Novel C 2-symmetric bis-oxazoline ligands

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Abstract

Two novel C 2-symmetric bis-oxazoline ligands were synthesized and their complexes with Cu(OAc)2 were studied as catalysts in the enantioselective Henry reaction of 4-nitrobenz-aldehyde with nitromethane giving high yield of nitro aldol with ee up to 40%.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. V. Veselovsky, A. V. Lozanova & E. A. Mistryukov

Authors
  1. V. V. Veselovsky
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  2. A. V. Lozanova
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  3. E. A. Mistryukov
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Corresponding author

Correspondence to V. V. Veselovsky.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2163–2165, November, 2012.

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Veselovsky, V.V., Lozanova, A.V. & Mistryukov, E.A. Novel C 2-symmetric bis-oxazoline ligands. Russ Chem Bull 61, 2180–2182 (2012). https://doi.org/10.1007/s11172-012-0307-z

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  • DOI: https://doi.org/10.1007/s11172-012-0307-z

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