Abstract
Diazotization of vicinal 1-amino-2-ethynyl-4-R-9,10-anthraquinones followed by a reaction with NaN3 gave 5-hydroxy-3-R-1H-naphtho[2,3-g]indazole-6,11-diones or 3-ethynyl-5-R-6H-anthra[1,9-cd]isoxazol-6-ones, depending on the substituents at the triply bonded C atom and in position 4 of the anthraquinone framework.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2071–2078, November, 2012.
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Vasilevsky, S.F., Stepanov, A.A. & Fadeev, D.S. Dual reactivity of diazonium salts derived from 1-amino-2-ethynyl-9,10-anthraquinones. Russ Chem Bull 61, 2088–2095 (2012). https://doi.org/10.1007/s11172-012-0292-2
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DOI: https://doi.org/10.1007/s11172-012-0292-2