Abstract
Palladium-catalyzed C-N-cross-coupling of N,N′-bis(bromobenzyl) diazacrown compounds with two equivalents of 1-aza-15-crown-5 and 1-aza-18-crown-6 ethers furnished trismacrocyclic compounds with isolated macrocycles. Macrotricyclic cryptands were obtained when diazacrown ethers were used as N-components.
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Based on the Materials of the XIX Mendeleev Congress on General and Applied Chemistry (September 25–30, 2011, Volgograd, Russia).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1459–1466, July, 2012.
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Yakushev, A.A., Anokhin, M.V., Averin, A.D. et al. Palladium-catalyzed amination in the synthesis of aza- and diazacrown trismacrocyclic compounds. Russ Chem Bull 61, 1474–1482 (2012). https://doi.org/10.1007/s11172-012-0191-6
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DOI: https://doi.org/10.1007/s11172-012-0191-6