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Chemical equilibrium in a heterogeneous fluid phase system: thermodynamic regularities and topology of phase diagrams

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Abstract

Singularities of the systems with simultaneous phase and chemical equilibria were examined. The thermodynamic regularities were revealed and topology of phase diagrams was presented for multicomponent heterogeneous systems including two or several equilibrium liquid phases (solution layering). The thermodynamic conditions for displacement of phase and chemical equilibrium are considered.

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  1. Department of Chemical Thermodynamics and Kinetics, Saint Petersburg State University, 26 Universitetsky prosp., 198504, Saint Petersburg, Russian Federation

    A. M. Toikka, M. A. Toikka & M. A. Trofimova

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  1. A. M. Toikka
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  2. M. A. Toikka
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0737–0747, April, 2012.

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Toikka, A.M., Toikka, M.A. & Trofimova, M.A. Chemical equilibrium in a heterogeneous fluid phase system: thermodynamic regularities and topology of phase diagrams. Russ Chem Bull 61, 741–751 (2012). https://doi.org/10.1007/s11172-012-0106-6

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